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Unusual magnetic behavior of SiCN/multiwalled carbon nanotubes nanocomposites

Francis, A. ; Riedel, R. (2009)
Unusual magnetic behavior of SiCN/multiwalled carbon nanotubes nanocomposites.
In: Journal of Applied Physics, 105 (7)
doi: 10.1063/1.3062958
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Multiwalled carbon nanotubes (MWCNTs) have been dispersed homogeneously throughout a preceramic polysilazane matrix. The homogenized mixture was then warm pressed and subsequently pyrolyzed in Ar atmosphere at 1100 °C, yielding an amorphous silicon carbonitride (SiCN)/MWCNT nanocomposite. The hysteresis loop of the 5 vol % CNT/SiCN composite revealed a ferromagneticlike behavior up to 5000 Oe and a semiconductinglike feature at a higher applied field. The magnetic behavior of CNT-rich composites is due mainly to defects and to the interaction between the nanotubes and the SiCN matrix, which is indicated by a shift in the G and D bands of graphitic carbon as determined by Raman spectroscopy. © 2009 American Institute of Physics

Typ des Eintrags: Artikel
Erschienen: 2009
Autor(en): Francis, A. ; Riedel, R.
Art des Eintrags: Bibliographie
Titel: Unusual magnetic behavior of SiCN/multiwalled carbon nanotubes nanocomposites
Sprache: Englisch
Publikationsjahr: 1 April 2009
Verlag: AIP
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Applied Physics
Jahrgang/Volume einer Zeitschrift: 105
(Heft-)Nummer: 7
DOI: 10.1063/1.3062958
Kurzbeschreibung (Abstract):

Multiwalled carbon nanotubes (MWCNTs) have been dispersed homogeneously throughout a preceramic polysilazane matrix. The homogenized mixture was then warm pressed and subsequently pyrolyzed in Ar atmosphere at 1100 °C, yielding an amorphous silicon carbonitride (SiCN)/MWCNT nanocomposite. The hysteresis loop of the 5 vol % CNT/SiCN composite revealed a ferromagneticlike behavior up to 5000 Oe and a semiconductinglike feature at a higher applied field. The magnetic behavior of CNT-rich composites is due mainly to defects and to the interaction between the nanotubes and the SiCN matrix, which is indicated by a shift in the G and D bands of graphitic carbon as determined by Raman spectroscopy. © 2009 American Institute of Physics

Freie Schlagworte: carbon nanotubes, diamagnetic materials, ferrimagnetic materials, magnetic hysteresis, nanocomposites, pyrolysis, silicon compounds, soft magnetic materials
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 12 Apr 2012 11:00
Letzte Änderung: 05 Mär 2013 10:00
PPN:
Sponsoren: This work was financially supported by the Alexander von Humboldt (AvH) foundation.
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