Ionescu, Emanuel ; Papendorf, Benjamin ; Kleebe, Hans-Joachim ; Riedel, Ralf (2010)
Polymer-Derived Silicon Oxycarbide/Hafnia Ceramic Nanocomposites. Part II: Stability Toward Decomposition and Microstructure Evolution at T≫1000°C.
In: Journal of the American Ceramic Society, 93 (6)
doi: 10.1111/j.1551-2916.2009.03527.x
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
This study presents first investigations on the high-temperature stability and microstructure evolution of SiOC/HfO2 ceramic nanocomposites. Polymer-derived SiOC/HfO2 ceramic nanocomposites have been prepared via chemical modification of a commercially available polysilsesquioxane by hafnium tetra (n-butoxide). The modified polysilsesquioxane-based materials were cross-linked and subsequently pyrolyzed at 1100°C in argon atmosphere to obtain SiOC/HfO2 ceramic nanocomposites. Annealing experiments at temperatures between 1300° and 1600°C were performed and the annealed materials were investigated with respect to chemical composition and microstructure. The ceramic nanocomposites presented here were found to exhibit a remarkably improved thermal stability up to 1600°C in comparison with hafnia-free silicon oxycarbide. Chemical analysis, X-ray diffraction, FTIR, and Raman spectroscopy as well as electron microscopy (SEM, TEM) studies revealed that the excellent thermal stability of the SiOC/HfO2 nanocomposites is a consequence of the in situ formation of hafnon (HfSiO4), which represents a concurrent reaction to the carbothermal decomposition of the SiOC matrix. Thus, by the annealing of SiOC/HfO2 materials at 1600°C, novel HfSiO4/SiC/C ceramic nanocomposites can be generated. The results presented emphasize the potential of these materials for application at high temperatures.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2010 |
| Autor(en): | Ionescu, Emanuel ; Papendorf, Benjamin ; Kleebe, Hans-Joachim ; Riedel, Ralf |
| Art des Eintrags: | Bibliographie |
| Titel: | Polymer-Derived Silicon Oxycarbide/Hafnia Ceramic Nanocomposites. Part II: Stability Toward Decomposition and Microstructure Evolution at T≫1000°C |
| Sprache: | Englisch |
| Publikationsjahr: | Juni 2010 |
| Verlag: | Wiley |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Journal of the American Ceramic Society |
| Jahrgang/Volume einer Zeitschrift: | 93 |
| (Heft-)Nummer: | 6 |
| DOI: | 10.1111/j.1551-2916.2009.03527.x |
| Kurzbeschreibung (Abstract): | This study presents first investigations on the high-temperature stability and microstructure evolution of SiOC/HfO2 ceramic nanocomposites. Polymer-derived SiOC/HfO2 ceramic nanocomposites have been prepared via chemical modification of a commercially available polysilsesquioxane by hafnium tetra (n-butoxide). The modified polysilsesquioxane-based materials were cross-linked and subsequently pyrolyzed at 1100°C in argon atmosphere to obtain SiOC/HfO2 ceramic nanocomposites. Annealing experiments at temperatures between 1300° and 1600°C were performed and the annealed materials were investigated with respect to chemical composition and microstructure. The ceramic nanocomposites presented here were found to exhibit a remarkably improved thermal stability up to 1600°C in comparison with hafnia-free silicon oxycarbide. Chemical analysis, X-ray diffraction, FTIR, and Raman spectroscopy as well as electron microscopy (SEM, TEM) studies revealed that the excellent thermal stability of the SiOC/HfO2 nanocomposites is a consequence of the in situ formation of hafnon (HfSiO4), which represents a concurrent reaction to the carbothermal decomposition of the SiOC matrix. Thus, by the annealing of SiOC/HfO2 materials at 1600°C, novel HfSiO4/SiC/C ceramic nanocomposites can be generated. The results presented emphasize the potential of these materials for application at high temperatures. |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Geowissenschaften > Fachgebiet Geomaterialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe |
| Hinterlegungsdatum: | 11 Apr 2012 11:23 |
| Letzte Änderung: | 13 Aug 2021 11:13 |
| PPN: | |
| Sponsoren: | Financial support by Fonds der Chemischen Industrie. |
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