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Visualization of Multipolar Longitudinal and Transversal Surface Plasmon Modes in Nanowire Dimers

Alber, Ina ; Sigle, Wilfried ; Müller, Sven ; Neumann, Reinhard ; Picht, Oliver ; Rauber, Markus ; Aken, Peter A. van ; Toimil-Molares, Maria Eugenia (2011)
Visualization of Multipolar Longitudinal and Transversal Surface Plasmon Modes in Nanowire Dimers.
In: ACS Nano, 5 (12)
doi: 10.1021/nn2035044
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

We study the transversal and longitudinal localized surface plasmon resonances in single nanowires and nanowire dimers excited by the fast traveling electron beam in a transmission electron microscope equipped with high-resolution electron energy-loss spectroscopy. Bright and dark longitudinal modes up to the fifth order are resolved on individual metallic nanowires. On nanowire dimers, mode splitting into bonding and antibonding is measured up to the third order for several dimers with various aspect ratio and controlled gap size. We observe that the electric field maxima of the bonding modes are shifted toward the gap, while the electric field maxima of the antibonding modes are shifted toward the dimer ends. Finally, we observe that the transversal mode is not detected in the region of the dimer gap and decays away from the rod more rapidly than the longitudinal modes.

Typ des Eintrags: Artikel
Erschienen: 2011
Autor(en): Alber, Ina ; Sigle, Wilfried ; Müller, Sven ; Neumann, Reinhard ; Picht, Oliver ; Rauber, Markus ; Aken, Peter A. van ; Toimil-Molares, Maria Eugenia
Art des Eintrags: Bibliographie
Titel: Visualization of Multipolar Longitudinal and Transversal Surface Plasmon Modes in Nanowire Dimers
Sprache: Englisch
Publikationsjahr: 27 Dezember 2011
Verlag: ACS Publications
Titel der Zeitschrift, Zeitung oder Schriftenreihe: ACS Nano
Jahrgang/Volume einer Zeitschrift: 5
(Heft-)Nummer: 12
DOI: 10.1021/nn2035044
Kurzbeschreibung (Abstract):

We study the transversal and longitudinal localized surface plasmon resonances in single nanowires and nanowire dimers excited by the fast traveling electron beam in a transmission electron microscope equipped with high-resolution electron energy-loss spectroscopy. Bright and dark longitudinal modes up to the fifth order are resolved on individual metallic nanowires. On nanowire dimers, mode splitting into bonding and antibonding is measured up to the third order for several dimers with various aspect ratio and controlled gap size. We observe that the electric field maxima of the bonding modes are shifted toward the gap, while the electric field maxima of the antibonding modes are shifted toward the dimer ends. Finally, we observe that the transversal mode is not detected in the region of the dimer gap and decays away from the rod more rapidly than the longitudinal modes.

Freie Schlagworte: transversal surface plasmon resonance, longitudinal surface plasmon resonances, bonding multipol order modes, antibonding multipol order modes, electron energy-loss spectroscopy, nanowire dimer synthesis
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialanalytik
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Ionenstrahlmodifizierte Materialien
Hinterlegungsdatum: 08 Mär 2012 16:17
Letzte Änderung: 19 Mär 2024 07:16
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