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Experimental and theoretical investigation on polarization reversal in unfatigued lead-zirconate-titanate ceramic

Zhukov, Sergey ; Genenko, Yuri A. ; Seggern, Heinz von (2010)
Experimental and theoretical investigation on polarization reversal in unfatigued lead-zirconate-titanate ceramic.
In: Journal of Applied Physics, 108 (1)
doi: 10.1063/1.3380844
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The dynamics of polarization switching in a soft lead-zirconate-titanate ceramic has been studied over a broad time window ranging from 10−6–106 for applied fields between 0.5 and 2.5 kV/mm. The classical Kolmogorov–Avrami–Ishibashi model of the polarization reversal was not able to satisfactory explain the obtained results. Therefore, a new concept for the polarization dynamics of ferroelectric ceramics has been suggested, which is based on two principal assumptions, (1) a strong dependence of the polarization switching time on the local electric field and (2) a random distribution of the local switching times caused by an intrinsic randomness in the field distribution within the system. Thereby the switching volume is composed as an ensemble of many regions with independent dynamics governed by local field exclusively. Such random field distribution could be well adjusted by a Gaussian distribution around the mean value of the field applied. A total polarization dependence on time and applied field was obtained in explicit form with only three fitting parameters which enabled a good description of the experimental results on polarization reversal in the whole time-field domain.

Typ des Eintrags: Artikel
Erschienen: 2010
Autor(en): Zhukov, Sergey ; Genenko, Yuri A. ; Seggern, Heinz von
Art des Eintrags: Bibliographie
Titel: Experimental and theoretical investigation on polarization reversal in unfatigued lead-zirconate-titanate ceramic
Sprache: Englisch
Publikationsjahr: Juli 2010
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Applied Physics
Jahrgang/Volume einer Zeitschrift: 108
(Heft-)Nummer: 1
DOI: 10.1063/1.3380844
Kurzbeschreibung (Abstract):

The dynamics of polarization switching in a soft lead-zirconate-titanate ceramic has been studied over a broad time window ranging from 10−6–106 for applied fields between 0.5 and 2.5 kV/mm. The classical Kolmogorov–Avrami–Ishibashi model of the polarization reversal was not able to satisfactory explain the obtained results. Therefore, a new concept for the polarization dynamics of ferroelectric ceramics has been suggested, which is based on two principal assumptions, (1) a strong dependence of the polarization switching time on the local electric field and (2) a random distribution of the local switching times caused by an intrinsic randomness in the field distribution within the system. Thereby the switching volume is composed as an ensemble of many regions with independent dynamics governed by local field exclusively. Such random field distribution could be well adjusted by a Gaussian distribution around the mean value of the field applied. A total polarization dependence on time and applied field was obtained in explicit form with only three fitting parameters which enabled a good description of the experimental results on polarization reversal in the whole time-field domain.

Freie Schlagworte: ferroelectric ceramics, Gaussian distribution, lead compounds, polarisation
Zusätzliche Informationen:

SFB 595 Cooperation B7,C5

Fachbereich(e)/-gebiet(e): DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung > Teilprojekt B7:Polarisation und Ladung in elektrisch ermüdeten Ferroelektrika
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > C - Modellierung > Teilprojekt C5: Phänomenologische Modellierung von Injektion, Transport und Rekombination in Bauelementen aus organischen Halbleitern sowie aus nichtorganischen Ferroelektrika
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > C - Modellierung
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung
Zentrale Einrichtungen
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche
DFG-Sonderforschungsbereiche (inkl. Transregio)
Hinterlegungsdatum: 15 Aug 2011 12:35
Letzte Änderung: 05 Mär 2013 09:51
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