Hinterstein, Manuel ; Schönau, Kristin A. ; Kling, Jens ; Fuess, Hartmut ; Knapp, Michael ; Kungl, Hans ; Hoffmann, Michael J. (2010)
Influence of lanthanum doping on the morphotropic phase boundary of lead zirconate titanate.
In: Journal of Applied Physics, 108 (2)
doi: 10.1063/1.3437399
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
A phase diagram for morphotropic (Pb0.985La0.01)(Zr1−xTix)O3 is proposed based on a combination of X-ray and neutron powder diffraction experiments and complemented by transmission electron microscopy. Dependent on composition three regions are characterized. The stability range of tetragonal microdomains for high Ti contents, the stability range of rhombohedral microdomains for low Ti contents, and an intermediate stability range of nanodomains. All three regions exhibit a corresponding low temperature configuration. Temperature dependent diffraction revealed that lanthanum doping reduces the sensitivity of the structure to changes in temperature and composition. A continuous transition from pseudorhombohedral to tetragonal symmetry with an intermediate two-phase region at the morphotropic phase boundary is observed. A similar transition of low temperature superstructure phases from pseudorhombohedral to pseudotetragonal with an intermediate monoclinic phase governed by a continuous change in the oxygen octahedral tilt system from a−a−a− over a−a−c− to a0a0c− is identified.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2010 |
| Autor(en): | Hinterstein, Manuel ; Schönau, Kristin A. ; Kling, Jens ; Fuess, Hartmut ; Knapp, Michael ; Kungl, Hans ; Hoffmann, Michael J. |
| Art des Eintrags: | Bibliographie |
| Titel: | Influence of lanthanum doping on the morphotropic phase boundary of lead zirconate titanate |
| Sprache: | Englisch |
| Publikationsjahr: | Juli 2010 |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Journal of Applied Physics |
| Jahrgang/Volume einer Zeitschrift: | 108 |
| (Heft-)Nummer: | 2 |
| DOI: | 10.1063/1.3437399 |
| Kurzbeschreibung (Abstract): | A phase diagram for morphotropic (Pb0.985La0.01)(Zr1−xTix)O3 is proposed based on a combination of X-ray and neutron powder diffraction experiments and complemented by transmission electron microscopy. Dependent on composition three regions are characterized. The stability range of tetragonal microdomains for high Ti contents, the stability range of rhombohedral microdomains for low Ti contents, and an intermediate stability range of nanodomains. All three regions exhibit a corresponding low temperature configuration. Temperature dependent diffraction revealed that lanthanum doping reduces the sensitivity of the structure to changes in temperature and composition. A continuous transition from pseudorhombohedral to tetragonal symmetry with an intermediate two-phase region at the morphotropic phase boundary is observed. A similar transition of low temperature superstructure phases from pseudorhombohedral to pseudotetragonal with an intermediate monoclinic phase governed by a continuous change in the oxygen octahedral tilt system from a−a−a− over a−a−c− to a0a0c− is identified. |
| Freie Schlagworte: | crystal symmetry, doping, lanthanum compounds, lead compounds, phase diagrams, titanium compounds, transmission electron microscopy, X-ray diffraction, zirconium compounds |
| Zusätzliche Informationen: | SFB 595 Cooperation A2, B3 |
| Fachbereich(e)/-gebiet(e): | Zentrale Einrichtungen DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > A - Synthese > Teilprojekt A2: Herstellung und Charakterisierung von PZT-Keramiken mit definierter Defektchemie DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung > Teilprojekt B3: Strukturelle Untersuchungen zur Aufklärung der elektrischen Ermüdung in PZT DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > A - Synthese DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche DFG-Sonderforschungsbereiche (inkl. Transregio) |
| Hinterlegungsdatum: | 10 Aug 2011 11:28 |
| Letzte Änderung: | 05 Mär 2013 09:51 |
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