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Composition dependence of the domain configuration and size in Pb(Zr[sub 1−x]Ti[sub x])O[sub 3] ceramics

Schmitt, Ljubomira A. ; Schönau, Kristin A. ; Theissmann, Ralf ; Fuess, Hartmut ; Kungl, Hans ; Hoffmann, Michael J. (2007)
Composition dependence of the domain configuration and size in Pb(Zr[sub 1−x]Ti[sub x])O[sub 3] ceramics.
In: Journal of Applied Physics, 101 (7)
doi: 10.1063/1.2715476
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The composition dependent variation of domain configuration and size in Pb(Zr1−xTix)O3 (PZT) has been investigated in a detailed transmission electron microscopy study in the range of 0.40 ⩽ x ⩽ 0.55. Single phase composition, Pb(Zr0.45Ti0.55)O3 and Pb(Zr0.60Ti0.40)O3, the former belonging to the tetragonal, the latter to the rhombohedral phase, feature small microdomain widths coupled with a pronounced bimodal domain distribution. Samples with compositions around the morphotropic phase boundary exhibit a decrease of bimodal distribution and an increase in microdomain width associated with nanodomain formation. The investigation of micro- and nanodomains, as well as the bimodal distribution of microdomains in undoped PZT ceramics, with respect to composition, is reported. We define nanodomains as “domains arranged within microdomains possessing a width of a few nanometers.” The strict alternation of the two orientation variants of microdomains is denoted as “bimodal domain distribution,” and is characterized by narrow and broad microdomains, which join each other in turn.

Typ des Eintrags: Artikel
Erschienen: 2007
Autor(en): Schmitt, Ljubomira A. ; Schönau, Kristin A. ; Theissmann, Ralf ; Fuess, Hartmut ; Kungl, Hans ; Hoffmann, Michael J.
Art des Eintrags: Bibliographie
Titel: Composition dependence of the domain configuration and size in Pb(Zr[sub 1−x]Ti[sub x])O[sub 3] ceramics
Sprache: Englisch
Publikationsjahr: April 2007
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Applied Physics
Jahrgang/Volume einer Zeitschrift: 101
(Heft-)Nummer: 7
DOI: 10.1063/1.2715476
Kurzbeschreibung (Abstract):

The composition dependent variation of domain configuration and size in Pb(Zr1−xTix)O3 (PZT) has been investigated in a detailed transmission electron microscopy study in the range of 0.40 ⩽ x ⩽ 0.55. Single phase composition, Pb(Zr0.45Ti0.55)O3 and Pb(Zr0.60Ti0.40)O3, the former belonging to the tetragonal, the latter to the rhombohedral phase, feature small microdomain widths coupled with a pronounced bimodal domain distribution. Samples with compositions around the morphotropic phase boundary exhibit a decrease of bimodal distribution and an increase in microdomain width associated with nanodomain formation. The investigation of micro- and nanodomains, as well as the bimodal distribution of microdomains in undoped PZT ceramics, with respect to composition, is reported. We define nanodomains as “domains arranged within microdomains possessing a width of a few nanometers.” The strict alternation of the two orientation variants of microdomains is denoted as “bimodal domain distribution,” and is characterized by narrow and broad microdomains, which join each other in turn.

Freie Schlagworte: lead compounds, ferroelectric ceramics, electric domains, transmission electron microscopy, ferroelectric switching, dielectric polarisation
Zusätzliche Informationen:

SFB 595 Cooperation A2, B3

Fachbereich(e)/-gebiet(e): DFG-Sonderforschungsbereiche (inkl. Transregio)
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche
Zentrale Einrichtungen
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > A - Synthese
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > A - Synthese > Teilprojekt A2: Herstellung und Charakterisierung von PZT-Keramiken mit definierter Defektchemie
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung > Teilprojekt B3: Strukturelle Untersuchungen zur Aufklärung der elektrischen Ermüdung in PZT
Hinterlegungsdatum: 27 Jul 2011 12:25
Letzte Änderung: 31 Jan 2019 15:21
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