Kleebe, Hans-Joachim ; Lauterbach, Stefan ; Silvestroni, Laura ; Kungl, Hans ; Hoffmann, Michael J. ; Erdem, Emre ; Eichel, Rüdiger-A. (2009)
Formation of magnetic grains in ferroelectric Pb[Zr0.6Ti0.4]O3
ceramics doped with Fe3+ above the solubility limit.
In: Applied Physics Letters, 94 (14)
doi: 10.1063/1.3103313
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
The effect of excess iron-doping in piezoelectric lead-zirconate-titanate (PZT) on the microstructure was investigated by means of transmission electron microscopy in conjunction with electron diffraction and energy dispersive x-ray spectroscopy analysis. Electron paramagnetic resonance (EPR) spectroscopy has been used to characterize the site of the iron functional centers. A crystalline secondary magnetic phase formed upon sintering, magnetoplumbite (PbFe12O19), has been unequivocally identified. Furthermore, the phase assemblage observed in the Fe3+-doped PZT 60/40 sample could be correlated with an exchange-coupled resonance in the EPR spectra.
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