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Effect of K0.5Na0.5NbO3on Properties at and off the Morphotropic Phase Boundary in Bi0.5Na0.5TiO3–Bi0.5K0.5TiO3Ceramics

Anton, Eva-Maria ; Jo, Wook ; Trodahl, Joe ; Damjanovic, Dragan ; Rödel, Jürgen (2011)
Effect of K0.5Na0.5NbO3on Properties at and off the Morphotropic Phase Boundary in Bi0.5Na0.5TiO3–Bi0.5K0.5TiO3Ceramics.
In: Japanese Journal of Applied Physics, 50 (5)
doi: 10.1143/JJAP.50.055802
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Lead-free (1-y)(Bi1/2Na1/2TiO3–xBi1/2K1/2TiO3)–yK0.5Na0.5NbO3 [(1-y)(BNT–xBKT)–yKNN] (0.1≤x≤0.6 and 0≤y≤0.05) ceramics were prepared with compositions both at as well as off the morphotropic phase boundary (MPB) of x=0.2 and y=0. It was found that KNN addition destabilizes a ferroelectric order in BNT–BKT at zero electric-field, resulting in low remanent polarization, remanent strain and effective small signal d33eff [23 pC/N for (x,y)=(0.2,0.05), 60 pC/N for (0.2, 0.02)], while it does not affect the maximum polarisation and strain at high fields and thus enhances large signal piezoelectric coefficient, d33* [200 pm/V for (0.2,0.05), 217 pm/V for (0.2,0.02)]. This effect of KNN was found to be independent from the MPB and thus equally high d33* values were obtained for compositions at and far off the MPB. Thus, adding KNN to BNT–BKT removes the restriction to remain at exactly MPB position and provides more flexibility while offering equal or even improved strain.

Typ des Eintrags: Artikel
Erschienen: 2011
Autor(en): Anton, Eva-Maria ; Jo, Wook ; Trodahl, Joe ; Damjanovic, Dragan ; Rödel, Jürgen
Art des Eintrags: Bibliographie
Titel: Effect of K0.5Na0.5NbO3on Properties at and off the Morphotropic Phase Boundary in Bi0.5Na0.5TiO3–Bi0.5K0.5TiO3Ceramics
Sprache: Englisch
Publikationsjahr: Mai 2011
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Japanese Journal of Applied Physics
Jahrgang/Volume einer Zeitschrift: 50
(Heft-)Nummer: 5
DOI: 10.1143/JJAP.50.055802
Kurzbeschreibung (Abstract):

Lead-free (1-y)(Bi1/2Na1/2TiO3–xBi1/2K1/2TiO3)–yK0.5Na0.5NbO3 [(1-y)(BNT–xBKT)–yKNN] (0.1≤x≤0.6 and 0≤y≤0.05) ceramics were prepared with compositions both at as well as off the morphotropic phase boundary (MPB) of x=0.2 and y=0. It was found that KNN addition destabilizes a ferroelectric order in BNT–BKT at zero electric-field, resulting in low remanent polarization, remanent strain and effective small signal d33eff [23 pC/N for (x,y)=(0.2,0.05), 60 pC/N for (0.2, 0.02)], while it does not affect the maximum polarisation and strain at high fields and thus enhances large signal piezoelectric coefficient, d33* [200 pm/V for (0.2,0.05), 217 pm/V for (0.2,0.02)]. This effect of KNN was found to be independent from the MPB and thus equally high d33* values were obtained for compositions at and far off the MPB. Thus, adding KNN to BNT–BKT removes the restriction to remain at exactly MPB position and provides more flexibility while offering equal or even improved strain.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 15 Jun 2011 08:18
Letzte Änderung: 05 Mär 2013 09:48
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