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Evaluation of domain wall motion in bipolar fatigued lead-zirconate-titanate: A study on reversible and irreversible contributions

Glaum, Julia ; Granzow, Torsten ; Rödel, Jürgen (2010)
Evaluation of domain wall motion in bipolar fatigued lead-zirconate-titanate: A study on reversible and irreversible contributions.
In: Journal of Applied Physics, 107 (10)
doi: 10.1063/1.3386461
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Mobility of ferroelectric domain walls is a critical factor in the fatigue of piezoelectric ceramics. Here, reversible and irreversible domain wall motion is evaluated for lead-zirconate-titanate both before and after fatigue cycling. To this end, the small-signal permittivity at different levels of bias field is compared to the large-signal permittivity, i.e., the first derivative of the polarization hysteresis loop. While the small-signal permittivity is just determined by the reversible processes due to the small electric excitation field, the large-signal permittivity reflects both reversible and irreversible contributions. The ratio of large- and small-signal permittivity is suggested as measure for the reversible contribution to the overall polarization change. Fatigue leads to a decrease in the small-signal permittivity and hence a general suppression of the reversible processes. Furthermore it causes a shift in the irreversible contributions to higher electric fields and a retarded backswitching when the external electric field is reduced after the maximum field value was reached. This reinforces the notion of bipolar electric fatigue caused by pinned domain walls due to agglomeration of charged defects in the sample bulk.

Typ des Eintrags: Artikel
Erschienen: 2010
Autor(en): Glaum, Julia ; Granzow, Torsten ; Rödel, Jürgen
Art des Eintrags: Bibliographie
Titel: Evaluation of domain wall motion in bipolar fatigued lead-zirconate-titanate: A study on reversible and irreversible contributions
Sprache: Englisch
Publikationsjahr: Mai 2010
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Applied Physics
Jahrgang/Volume einer Zeitschrift: 107
(Heft-)Nummer: 10
DOI: 10.1063/1.3386461
Kurzbeschreibung (Abstract):

Mobility of ferroelectric domain walls is a critical factor in the fatigue of piezoelectric ceramics. Here, reversible and irreversible domain wall motion is evaluated for lead-zirconate-titanate both before and after fatigue cycling. To this end, the small-signal permittivity at different levels of bias field is compared to the large-signal permittivity, i.e., the first derivative of the polarization hysteresis loop. While the small-signal permittivity is just determined by the reversible processes due to the small electric excitation field, the large-signal permittivity reflects both reversible and irreversible contributions. The ratio of large- and small-signal permittivity is suggested as measure for the reversible contribution to the overall polarization change. Fatigue leads to a decrease in the small-signal permittivity and hence a general suppression of the reversible processes. Furthermore it causes a shift in the irreversible contributions to higher electric fields and a retarded backswitching when the external electric field is reduced after the maximum field value was reached. This reinforces the notion of bipolar electric fatigue caused by pinned domain walls due to agglomeration of charged defects in the sample bulk.

Zusätzliche Informationen:

SFB 595 D1

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > D - Bauteileigenschaften > Teilprojekt D1: Mesoskopische und makroskopische Ermüdung in dotierten ferroelektrischen Keramiken
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > D - Bauteileigenschaften
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung
Zentrale Einrichtungen
DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche
DFG-Sonderforschungsbereiche (inkl. Transregio)
Hinterlegungsdatum: 20 Jun 2011 08:54
Letzte Änderung: 05 Mär 2013 09:48
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