Jo, Wook ; Rödel, Jürgen ; Lee, Jong-Sook ; Baik, Yoon-Hee ; Park, Chan (2010)
Effect of substitution of K for Na on the ferroelectric stability and properties in (Bi0.5Na1/2)TiO3-BaTiO3-(K1/2N1/2)NbO3.
In: Functional Materials Letters, 03 (01)
doi: 10.1142/S179360471000083X
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
The effect of an isovalent chemical variation in A site cations on the stability of ferroelectric order and consequent changes in the electrical properties of ferroelectric 0.93(Bi1/2Na1/2)TiO3-0.05BaTiO3-0.02(K0.5Na0.5)NbO3 (0.93BNT-0.05BT-0.02KNN) lead-free piezoceramic at the morphotropic phase boundary (MPB) was investigated by substituting K for Na. X-ray diffraction analysis reveals that all the studied compositions undergo an irreversible phase transition from a pseudocubic to a mixture of rhombohedral and tetragonal phases during poling. In spite of the absence of an obvious structural difference, both electric-field-induced strain and polarization hysteresis loops show a clear distinction. It was found that the effect of substitution is so drastic that about 0.5 at% substitution renders the material softer and more than 1.0 at% results in a significant destabilization of the ferroelectric order. However, no notable difference in the temperature dependent permittivity measurements was detected, which suggests that the depoling of these materials has some other origin than a symmetry-breaking phase transition.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2010 |
| Autor(en): | Jo, Wook ; Rödel, Jürgen ; Lee, Jong-Sook ; Baik, Yoon-Hee ; Park, Chan |
| Art des Eintrags: | Bibliographie |
| Titel: | Effect of substitution of K for Na on the ferroelectric stability and properties in (Bi0.5Na1/2)TiO3-BaTiO3-(K1/2N1/2)NbO3 |
| Sprache: | Englisch |
| Publikationsjahr: | März 2010 |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Functional Materials Letters |
| Jahrgang/Volume einer Zeitschrift: | 03 |
| (Heft-)Nummer: | 01 |
| DOI: | 10.1142/S179360471000083X |
| Kurzbeschreibung (Abstract): | The effect of an isovalent chemical variation in A site cations on the stability of ferroelectric order and consequent changes in the electrical properties of ferroelectric 0.93(Bi1/2Na1/2)TiO3-0.05BaTiO3-0.02(K0.5Na0.5)NbO3 (0.93BNT-0.05BT-0.02KNN) lead-free piezoceramic at the morphotropic phase boundary (MPB) was investigated by substituting K for Na. X-ray diffraction analysis reveals that all the studied compositions undergo an irreversible phase transition from a pseudocubic to a mixture of rhombohedral and tetragonal phases during poling. In spite of the absence of an obvious structural difference, both electric-field-induced strain and polarization hysteresis loops show a clear distinction. It was found that the effect of substitution is so drastic that about 0.5 at% substitution renders the material softer and more than 1.0 at% results in a significant destabilization of the ferroelectric order. However, no notable difference in the temperature dependent permittivity measurements was detected, which suggests that the depoling of these materials has some other origin than a symmetry-breaking phase transition. |
| Freie Schlagworte: | Lead-free piezoceramics; bismuth sodium titanate; electric-field-induced phase transition |
| Zusätzliche Informationen: | SFB 595 A1 |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > A - Synthese > Teilprojekt A1: Herstellung keramischer, texturierter Akuatoren mit hoher Dehnung DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > A - Synthese DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung Zentrale Einrichtungen DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche DFG-Sonderforschungsbereiche (inkl. Transregio) |
| Hinterlegungsdatum: | 20 Jun 2011 08:40 |
| Letzte Änderung: | 05 Mär 2013 09:48 |
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