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Comparison of the Temperature-Dependent Ferroelastic Behavior of Hard and Soft Lead Zirconate Titanate Ceramics

Marsilius, Mie ; Webber, Kyle G. ; Aulbach, Emil ; Granzow, Torsten (2010)
Comparison of the Temperature-Dependent Ferroelastic Behavior of Hard and Soft Lead Zirconate Titanate Ceramics.
In: Journal of the American Ceramic Society, 93 (9)
doi: 10.1111/j.1551-2916.2010.03801.x
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The ferroelastic properties of a hard acceptor-doped lead zirconate titanate (PZT) ceramic are investigated between room temperature and 300°C. Comparison with a soft PZT shows that acceptor doping has a stronger influence on mechanically induced domain switching than on switching caused by electric fields. A quantitative analysis of spontaneous and remanent strain and polarization indicates that poling in the soft material is dominated by 180° domain processes, while non-180° processes dominate the strain behavior. If the mechanical load exceeds a threshold level, the “hardening” effect of the acceptor doping vanishes, and hard and soft materials behave identically. The results are discussed based on the defect dipole model and the charge drift model for hardening and aging in acceptor-doped ferroelectric ceramics.

Typ des Eintrags: Artikel
Erschienen: 2010
Autor(en): Marsilius, Mie ; Webber, Kyle G. ; Aulbach, Emil ; Granzow, Torsten
Art des Eintrags: Bibliographie
Titel: Comparison of the Temperature-Dependent Ferroelastic Behavior of Hard and Soft Lead Zirconate Titanate Ceramics
Sprache: Englisch
Publikationsjahr: September 2010
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the American Ceramic Society
Jahrgang/Volume einer Zeitschrift: 93
(Heft-)Nummer: 9
DOI: 10.1111/j.1551-2916.2010.03801.x
Kurzbeschreibung (Abstract):

The ferroelastic properties of a hard acceptor-doped lead zirconate titanate (PZT) ceramic are investigated between room temperature and 300°C. Comparison with a soft PZT shows that acceptor doping has a stronger influence on mechanically induced domain switching than on switching caused by electric fields. A quantitative analysis of spontaneous and remanent strain and polarization indicates that poling in the soft material is dominated by 180° domain processes, while non-180° processes dominate the strain behavior. If the mechanical load exceeds a threshold level, the “hardening” effect of the acceptor doping vanishes, and hard and soft materials behave identically. The results are discussed based on the defect dipole model and the charge drift model for hardening and aging in acceptor-doped ferroelectric ceramics.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Elektromechanik von Oxiden
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 17 Jun 2011 12:28
Letzte Änderung: 28 Feb 2014 09:06
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