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Thermoelectric properties and texture evaluation of Ca3Co4O9 prepared by a cost-effective multisheet cofiring technique

Kwon, O-Jong ; Jo, Wook ; Ko, Kyeong-Eun ; Kim, Jae-Yeol ; Bae, Sung-Hwan ; Koo, Hyun ; Jeong, Seong-Min ; Kim, Jin-Sang ; Park, Chan (2011)
Thermoelectric properties and texture evaluation of Ca3Co4O9 prepared by a cost-effective multisheet cofiring technique.
In: Journal of Materials Science, 46 (9)
doi: 10.1007/s10853-010-5163-3
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Highly textured Ca3Co4O9 thermoelectrics were fabricated by a so-called multisheet cofiring (MSC) technique in combination with the commonly practiced spark plasma sintering (SPS) technique. X-ray diffraction analysis revealed that the MSC technique significantly enhances the degree of texture compared with the conventional SPS technique. This was confirmed by microstructure analysis performed on polished and chemically etched specimens. The power factor and the thermoelectric figure of merit for the specimen produced by the MSC technique were estimated to be ~5.2 × 10−4 W/mK2 and ~0.4, respectively, both of which are ~20% larger than those of the normally processed specimens. A comparative study of the thermoelectric properties, such as electrical resistivity and Seebeck coefficient, clearly demonstrated that texture mainly influences the electrical resistivity and consequently enhances the thermoelectric properties.

Typ des Eintrags: Artikel
Erschienen: 2011
Autor(en): Kwon, O-Jong ; Jo, Wook ; Ko, Kyeong-Eun ; Kim, Jae-Yeol ; Bae, Sung-Hwan ; Koo, Hyun ; Jeong, Seong-Min ; Kim, Jin-Sang ; Park, Chan
Art des Eintrags: Bibliographie
Titel: Thermoelectric properties and texture evaluation of Ca3Co4O9 prepared by a cost-effective multisheet cofiring technique
Sprache: Englisch
Publikationsjahr: Mai 2011
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Materials Science
Jahrgang/Volume einer Zeitschrift: 46
(Heft-)Nummer: 9
DOI: 10.1007/s10853-010-5163-3
Kurzbeschreibung (Abstract):

Highly textured Ca3Co4O9 thermoelectrics were fabricated by a so-called multisheet cofiring (MSC) technique in combination with the commonly practiced spark plasma sintering (SPS) technique. X-ray diffraction analysis revealed that the MSC technique significantly enhances the degree of texture compared with the conventional SPS technique. This was confirmed by microstructure analysis performed on polished and chemically etched specimens. The power factor and the thermoelectric figure of merit for the specimen produced by the MSC technique were estimated to be ~5.2 × 10−4 W/mK2 and ~0.4, respectively, both of which are ~20% larger than those of the normally processed specimens. A comparative study of the thermoelectric properties, such as electrical resistivity and Seebeck coefficient, clearly demonstrated that texture mainly influences the electrical resistivity and consequently enhances the thermoelectric properties.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 18 Mai 2011 15:20
Letzte Änderung: 05 Mär 2013 09:47
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