Zuo, Ruzhong and Rödel, Jürgen and Chen, Renzheng and Li, Longtu (2006):
Sintering and Electrical Properties of Lead-Free Na0.5K0.5NbO3 Piezoelectric Ceramics.
89, In: Journal of the American Ceramic Society, (6), pp. 2010-2015, ISSN 0002-7820, [Online-Edition: http://dx.doi.org/10.1111/j.1551-2916.2006.00991.x],
[Article]
Abstract
Lead-free Na0.5K0.5NbO3 (NKN) piezoelectric ceramics were fairly well densified at a relatively low temperature under atmospheric conditions. A relative density of 96%–99% can be achieved by either using high-energy attrition milling or adding 1 mol% oxide additives. It is suggested that ultra-fine starting powders by active milling or oxygen vacancies and even liquid phases from B-site oxide additives mainly lead to improved sintering. Not only were dielectric properties influenced by oxide additives, such as the Curie temperature (Tc) and dielectric loss (D), but also the ferroelectricity was modified. A relatively large remanent polarization was produced, ranging from 16 μC/cm2 for pure NKN to 23 μC/cm2 for ZnO-added NKN samples. The following dielectric and piezoelectric properties were obtained: relative permittivity ɛT33/ɛ0=570–650, planar mode electromechanical coupling factor, kp=32%–44%, and piezoelectric strain constant, d33=92–117 pC/N.
| Item Type: | Article |
|---|---|
| Erschienen: | 2006 |
| Creators: | Zuo, Ruzhong and Rödel, Jürgen and Chen, Renzheng and Li, Longtu |
| Title: | Sintering and Electrical Properties of Lead-Free Na0.5K0.5NbO3 Piezoelectric Ceramics |
| Language: | English |
| Abstract: | Lead-free Na0.5K0.5NbO3 (NKN) piezoelectric ceramics were fairly well densified at a relatively low temperature under atmospheric conditions. A relative density of 96%–99% can be achieved by either using high-energy attrition milling or adding 1 mol% oxide additives. It is suggested that ultra-fine starting powders by active milling or oxygen vacancies and even liquid phases from B-site oxide additives mainly lead to improved sintering. Not only were dielectric properties influenced by oxide additives, such as the Curie temperature (Tc) and dielectric loss (D), but also the ferroelectricity was modified. A relatively large remanent polarization was produced, ranging from 16 μC/cm2 for pure NKN to 23 μC/cm2 for ZnO-added NKN samples. The following dielectric and piezoelectric properties were obtained: relative permittivity ɛT33/ɛ0=570–650, planar mode electromechanical coupling factor, kp=32%–44%, and piezoelectric strain constant, d33=92–117 pC/N. |
| Journal or Publication Title: | Journal of the American Ceramic Society |
| Volume: | 89 |
| Number: | 6 |
| Divisions: | 11 Department of Materials and Earth Sciences 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis > Subproject A1: Manufacturing of ceramic, textured actuators with high strain DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue Zentrale Einrichtungen DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres DFG-Collaborative Research Centres (incl. Transregio) |
| Date Deposited: | 18 May 2011 15:20 |
| Official URL: | http://dx.doi.org/10.1111/j.1551-2916.2006.00991.x |
| Additional Information: | SFB 595 A1 |
| Identification Number: | doi:10.1111/j.1551-2916.2006.00991.x |
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