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Uniaxial viscosity of gadolinium-doped ceria determined by discontinuous sinter forging

Chang, Jaemyung ; Guillon, Olivier ; Rödel, Jürgen ; Kang, Suk-Joong L. (2007)
Uniaxial viscosity of gadolinium-doped ceria determined by discontinuous sinter forging.
In: Journal of the European Ceramic Society, 27 (10)
doi: 10.1016/j.jeurceramsoc.2007.01.003
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The sintering behaviour of nanocrystalline gadolinium-doped ceria was investigated. The uniaxial viscosity determined from isothermal discontinuous sinter forging experiments. It increased dramatically during sintering from a few GPa·s at 85% to not, vert, similar120 GPa·s at 97% relative density. These values, however, are much lower than those measured for other oxide materials with submicron sizes because of much finer grain size. Since the experiments were done under isothermal conditions, it is possible to evaluate separately the effects of the relative density and the grain size. Due to grain coarsening, the effect of grain size becomes significant at high relative density, as some available models predict. It was found that Rahaman's model best fit the experimental data.

Typ des Eintrags: Artikel
Erschienen: 2007
Autor(en): Chang, Jaemyung ; Guillon, Olivier ; Rödel, Jürgen ; Kang, Suk-Joong L.
Art des Eintrags: Bibliographie
Titel: Uniaxial viscosity of gadolinium-doped ceria determined by discontinuous sinter forging
Sprache: Englisch
Publikationsjahr: September 2007
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the European Ceramic Society
Jahrgang/Volume einer Zeitschrift: 27
(Heft-)Nummer: 10
DOI: 10.1016/j.jeurceramsoc.2007.01.003
Kurzbeschreibung (Abstract):

The sintering behaviour of nanocrystalline gadolinium-doped ceria was investigated. The uniaxial viscosity determined from isothermal discontinuous sinter forging experiments. It increased dramatically during sintering from a few GPa·s at 85% to not, vert, similar120 GPa·s at 97% relative density. These values, however, are much lower than those measured for other oxide materials with submicron sizes because of much finer grain size. Since the experiments were done under isothermal conditions, it is possible to evaluate separately the effects of the relative density and the grain size. Due to grain coarsening, the effect of grain size becomes significant at high relative density, as some available models predict. It was found that Rahaman's model best fit the experimental data.

Freie Schlagworte: Sintering; Viscous behaviour; CeO2; Fuel cells
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 18 Mai 2011 15:19
Letzte Änderung: 05 Mär 2013 09:47
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