Gaube, Johann ; Klein, Hans-Friedrich (2010)
Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis.
In: Applied Catalysis A: General, 374 (1-2)
doi: 10.1016/j.apcata.2009.11.039
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
The recently proposed hypothesis of two incompatible mechanisms of chain growth based on CH₂- and CO-insertion is furthermore supported by a detailed interpretation of the ¹³CH₂N₂ co-feeding experiments of Maitlis and co-workers and of the selectivity of branched hydrocarbons.
The carbon number distribution is discussed considering in particular the role of readsorption and incorporation of 1-alkenes and its subsequent chain growth.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2010 |
| Autor(en): | Gaube, Johann ; Klein, Hans-Friedrich |
| Art des Eintrags: | Bibliographie |
| Titel: | Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis |
| Sprache: | Englisch |
| Publikationsjahr: | 1 Februar 2010 |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Applied Catalysis A: General |
| Jahrgang/Volume einer Zeitschrift: | 374 |
| (Heft-)Nummer: | 1-2 |
| DOI: | 10.1016/j.apcata.2009.11.039 |
| Kurzbeschreibung (Abstract): | The recently proposed hypothesis of two incompatible mechanisms of chain growth based on CH₂- and CO-insertion is furthermore supported by a detailed interpretation of the ¹³CH₂N₂ co-feeding experiments of Maitlis and co-workers and of the selectivity of branched hydrocarbons. The carbon number distribution is discussed considering in particular the role of readsorption and incorporation of 1-alkenes and its subsequent chain growth. |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Anorganische Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie 07 Fachbereich Chemie |
| Hinterlegungsdatum: | 10 Jan 2011 12:30 |
| Letzte Änderung: | 05 Mär 2013 09:44 |
| PPN: | |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
 |
Frage zum Eintrag |
Optionen (nur für Redakteure)
 |
Redaktionelle Details anzeigen |
Drucken
Impressum