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Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis

Gaube, Johann and Klein, Hans-Friedrich (2010):
Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis.
In: Applied Catalysis A: General, pp. 120-125, 374, (1-2), ISSN 0926860X, [Online-Edition: http://dx.doi.org/10.1016/j.apcata.2009.11.039],
[Article]

Abstract

The recently proposed hypothesis of two incompatible mechanisms of chain growth based on CH₂- and CO-insertion is furthermore supported by a detailed interpretation of the ¹³CH₂N₂ co-feeding experiments of Maitlis and co-workers and of the selectivity of branched hydrocarbons.

The carbon number distribution is discussed considering in particular the role of readsorption and incorporation of 1-alkenes and its subsequent chain growth.

Item Type: Article
Erschienen: 2010
Creators: Gaube, Johann and Klein, Hans-Friedrich
Title: Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis
Language: English
Abstract:

The recently proposed hypothesis of two incompatible mechanisms of chain growth based on CH₂- and CO-insertion is furthermore supported by a detailed interpretation of the ¹³CH₂N₂ co-feeding experiments of Maitlis and co-workers and of the selectivity of branched hydrocarbons.

The carbon number distribution is discussed considering in particular the role of readsorption and incorporation of 1-alkenes and its subsequent chain growth.

Journal or Publication Title: Applied Catalysis A: General
Volume: 374
Number: 1-2
Divisions: 07 Department of Chemistry > Fachgebiet Anorganische Chemie
07 Department of Chemistry > Fachgebiet Technische Chemie
07 Department of Chemistry
Date Deposited: 10 Jan 2011 12:30
Official URL: http://dx.doi.org/10.1016/j.apcata.2009.11.039
Identification Number: doi:10.1016/j.apcata.2009.11.039
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