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Novel Surface Vibrational Spectroscopy: Infrared-Infrared-Visible Sum-Frequency Generation

Bonn, Mischa ; Hess, Christian ; Miners, James ; Heinz, Tony ; Bakker, Huib ; Cho, Minhaeng (2001)
Novel Surface Vibrational Spectroscopy: Infrared-Infrared-Visible Sum-Frequency Generation.
In: Physical Review Letters, 86 (8)
doi: 10.1103/PhysRevLett.86.1566
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

A novel type of surface vibrational sum-frequency generation spectroscopy is presented that enables a highly specific measurement of the coupling of molecules on surfaces. With this doubly vibrationally resonant technique, two-dimensional vibrational spectroscopy of molecules on surfaces becomes possible. The technique is demonstrated for the C-O stretch vibration of CO on a ruthenium (001) surface. It allows for the determination of the intermolecular coupling strength of dipole-coupled CO molecules on the surface.

Typ des Eintrags: Artikel
Erschienen: 2001
Autor(en): Bonn, Mischa ; Hess, Christian ; Miners, James ; Heinz, Tony ; Bakker, Huib ; Cho, Minhaeng
Art des Eintrags: Bibliographie
Titel: Novel Surface Vibrational Spectroscopy: Infrared-Infrared-Visible Sum-Frequency Generation
Sprache: Englisch
Publikationsjahr: 2001
Ort: College Park, MD
Verlag: American Physical Society
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Physical Review Letters
Jahrgang/Volume einer Zeitschrift: 86
(Heft-)Nummer: 8
DOI: 10.1103/PhysRevLett.86.1566
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Kurzbeschreibung (Abstract):

A novel type of surface vibrational sum-frequency generation spectroscopy is presented that enables a highly specific measurement of the coupling of molecules on surfaces. With this doubly vibrationally resonant technique, two-dimensional vibrational spectroscopy of molecules on surfaces becomes possible. The technique is demonstrated for the C-O stretch vibration of CO on a ruthenium (001) surface. It allows for the determination of the intermolecular coupling strength of dipole-coupled CO molecules on the surface.

Hinterlegungsdatum: 04 Nov 2010 15:26
Letzte Änderung: 24 Apr 2024 14:21
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