Schneider, Jörg J. ; Hoffmann, Rudolf C. ; Engstler, Jörg ; Dilfer, Stefan ; Klyszcz, Andreas ; Erdem, Emre ; Jakes, Peter ; Eichel, Rüdiger-A. (2009)
Zinc oxide derived from single source precursor chemistry under chimie douce conditions: Formation pathway, defect chemistry and possible applications in thin film printing.
In: Journal of Materials Chemistry, 19 (10)
doi: 10.1039/b816376f
Artikel, Bibliographie
Dies ist die neueste Version dieses Eintrags.
Kurzbeschreibung (Abstract)
A series of zinc complexes with oximate ligands is investigated for their suitability as precursors for zinc oxide in inkjet printing. The variation of hydrogen and alkyl groups in the side chains of the oximate framework (R1–ON–C2O2–R2) of the corresponding zinc complexes influences the decomposition temperature, and also important parameters such as solubility and wettability. Detailed investigations of the degradation mechanism reveal their behavior as excellent single source precursors for ZnO under very mild (chimie douce) conditions. Best results for the formation of zinc oxide thin films are obtained with solutions of [2-(methoxyimino)propanato]zinc in methoxyethanol. By calcincation well adherent (tensile strength of 1.95 (±0.95) MPa) nanocrystalline films of zincite are formed. This technique is applied for inkjet printing of ceramic layers on polyethylene-terephthalate thin films. Results of EPR spectroscopy studies on the ZnO nanoparticles are in accord with a core–shell model in which the grain particles of the core consist of vacancy centers which are electronically different from the surrounding shell of the ZnO nanoparticles.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2009 |
| Autor(en): | Schneider, Jörg J. ; Hoffmann, Rudolf C. ; Engstler, Jörg ; Dilfer, Stefan ; Klyszcz, Andreas ; Erdem, Emre ; Jakes, Peter ; Eichel, Rüdiger-A. |
| Art des Eintrags: | Bibliographie |
| Titel: | Zinc oxide derived from single source precursor chemistry under chimie douce conditions: Formation pathway, defect chemistry and possible applications in thin film printing |
| Sprache: | Englisch |
| Publikationsjahr: | Februar 2009 |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Journal of Materials Chemistry |
| Jahrgang/Volume einer Zeitschrift: | 19 |
| (Heft-)Nummer: | 10 |
| DOI: | 10.1039/b816376f |
| Kurzbeschreibung (Abstract): | A series of zinc complexes with oximate ligands is investigated for their suitability as precursors for zinc oxide in inkjet printing. The variation of hydrogen and alkyl groups in the side chains of the oximate framework (R1–ON–C2O2–R2) of the corresponding zinc complexes influences the decomposition temperature, and also important parameters such as solubility and wettability. Detailed investigations of the degradation mechanism reveal their behavior as excellent single source precursors for ZnO under very mild (chimie douce) conditions. Best results for the formation of zinc oxide thin films are obtained with solutions of [2-(methoxyimino)propanato]zinc in methoxyethanol. By calcincation well adherent (tensile strength of 1.95 (±0.95) MPa) nanocrystalline films of zincite are formed. This technique is applied for inkjet printing of ceramic layers on polyethylene-terephthalate thin films. Results of EPR spectroscopy studies on the ZnO nanoparticles are in accord with a core–shell model in which the grain particles of the core consist of vacancy centers which are electronically different from the surrounding shell of the ZnO nanoparticles. |
| Freie Schlagworte: | NANOCRYSTALLINE ZNO PARTICLES; FIELD-EFFECT TRANSISTORS; THERMAL-DECOMPOSITION; VISIBLE EMISSION; GAS-PHASE; LUMINESCENCE; TEMPERATURE; MECHANISM; ELECTRONICS; DEPOSITION |
| Zusätzliche Informationen: | SFB 595 B1 |
| Fachbereich(e)/-gebiet(e): | 16 Fachbereich Maschinenbau 16 Fachbereich Maschinenbau > Institut für Druckmaschinen und Druckverfahren (IDD) DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung > Teilprojekt B1: EPR Untersuchung von Defekten in ferroelektrischen keramischen Werkstoffen DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung Zentrale Einrichtungen DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche DFG-Sonderforschungsbereiche (inkl. Transregio) |
| Hinterlegungsdatum: | 27 Jul 2009 11:37 |
| Letzte Änderung: | 05 Mär 2013 09:21 |
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- Zinc oxide derived from single source precursor chemistry under chimie douce conditions: Formation pathway, defect chemistry and possible applications in thin film printing. (deposited 27 Jul 2009 11:37) [Gegenwärtig angezeigt]
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