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Ablation behavior of ZrC-SiHfOC-MoSi₂ coating for carbon/carbon composites under Ar-O₂ plasma flame

Zhang, Xuemeng ; Zhang, Yuyu ; Fan, Kaifei ; Riedel, Ralf ; Li, Hongbin ; Sun, Jia ; Li, Hejun (2024)
Ablation behavior of ZrC-SiHfOC-MoSi₂ coating for carbon/carbon composites under Ar-O₂ plasma flame.
In: Corrosion Science, 231
doi: 10.1016/j.corsci.2024.111944
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

To improve ablation resistance of ZrC-SiMOC-based (M = transition metal) coatings, a ZrC-SiHfOC-MoSi₂ coating was investigated. The results showed that the MoSi₂ shell limits the decomposition of SiC under SAPS and decreases pores of the coating. ZrC-SiHfOC coating showed large -area peeling after an Ar-O₂ plasma flame ablation for 90s. In contrast, ZrC-SiHfOC-MoSi₂ coating revealed low ablation rates after ablation for 360s, with the mass and linear ablation rates of -0.05 mg/s and 0.14 mu m/s, respectively. MoSi₂ provides rich SiO₂ to form ZrSiO₄ to reduce the damage by plasma flame, thereby improving the ablation resistance of ZrC-based coatings.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Zhang, Xuemeng ; Zhang, Yuyu ; Fan, Kaifei ; Riedel, Ralf ; Li, Hongbin ; Sun, Jia ; Li, Hejun
Art des Eintrags: Bibliographie
Titel: Ablation behavior of ZrC-SiHfOC-MoSi₂ coating for carbon/carbon composites under Ar-O₂ plasma flame
Sprache: Englisch
Publikationsjahr: 1 Mai 2024
Ort: Amsterdam
Verlag: Elsevier
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Corrosion Science
Jahrgang/Volume einer Zeitschrift: 231
DOI: 10.1016/j.corsci.2024.111944
Kurzbeschreibung (Abstract):

To improve ablation resistance of ZrC-SiMOC-based (M = transition metal) coatings, a ZrC-SiHfOC-MoSi₂ coating was investigated. The results showed that the MoSi₂ shell limits the decomposition of SiC under SAPS and decreases pores of the coating. ZrC-SiHfOC coating showed large -area peeling after an Ar-O₂ plasma flame ablation for 90s. In contrast, ZrC-SiHfOC-MoSi₂ coating revealed low ablation rates after ablation for 360s, with the mass and linear ablation rates of -0.05 mg/s and 0.14 mu m/s, respectively. MoSi₂ provides rich SiO₂ to form ZrSiO₄ to reduce the damage by plasma flame, thereby improving the ablation resistance of ZrC-based coatings.

Freie Schlagworte: ZrC, Polymer -Derived Ceramics (PDCs), C/C Composites, Plasma Spraying, Core -Shell Powders
ID-Nummer: Artikel-ID: 111944
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Werkstofftechnik und Ressourcenmanagement
Hinterlegungsdatum: 17 Jan 2025 12:42
Letzte Änderung: 17 Jan 2025 12:42
PPN: 525402276
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