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Heterogeneous oxidation behavior and kinetic mechanisms of SiBCN ceramic with structure of MA-SiBCN coated by PDCs-SiBCN

Niu, Zi-bo ; Li, Daxin ; Jia, Dechang ; Yang, Zhihua ; Lin, Kunpeng ; Colombo, Paolo ; Riedel, Ralf ; Zhou, Yu (2024)
Heterogeneous oxidation behavior and kinetic mechanisms of SiBCN ceramic with structure of MA-SiBCN coated by PDCs-SiBCN.
In: Journal of the European Ceramic Society, 44 (3)
doi: 10.1016/j.jeurceramsoc.2023.10.040
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

In this study, SiBCN ceramics with a structure of three-dimensional PDCs-SBCN network structure coated MASiBCN (MA@PDCs-SiBCN) were fabricated, which significantly improved the sintering activity and oxidation performance. The effect of MA@PDCs-SiBCN structure on oxidation behaviors and kinetics of oxide layer growth of the SiBCN ceramics at 1500 degrees C was investigated, indicating that the significantly improved oxidation resistance is attributed to the different heterogeneous oxidation behaviors, especially in the initial stage. Therefore, the heterogeneous oxidation behaviors and kinetic laws of different phases in MA@PDCs-SiBCN ceramics at different temperature ranges and their effects on structural evolution and oxide layer composition were analyzed by comparison with the MA-SiBCN ceramics. The significantly improved oxidation resistance of MA@PDCsSiBCN ceramics should be attributed to the inhibition of MA@PDCs-SiBCN structure to heterogeneous oxidation, especially the consumption of t-C, and different oxide layer composition generated from microcrystalline structure rather than nanocapsule-like crystalline structure.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Niu, Zi-bo ; Li, Daxin ; Jia, Dechang ; Yang, Zhihua ; Lin, Kunpeng ; Colombo, Paolo ; Riedel, Ralf ; Zhou, Yu
Art des Eintrags: Bibliographie
Titel: Heterogeneous oxidation behavior and kinetic mechanisms of SiBCN ceramic with structure of MA-SiBCN coated by PDCs-SiBCN
Sprache: Englisch
Publikationsjahr: März 2024
Ort: Amsterdam
Verlag: Elsevier
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the European Ceramic Society
Jahrgang/Volume einer Zeitschrift: 44
(Heft-)Nummer: 3
DOI: 10.1016/j.jeurceramsoc.2023.10.040
Kurzbeschreibung (Abstract):

In this study, SiBCN ceramics with a structure of three-dimensional PDCs-SBCN network structure coated MASiBCN (MA@PDCs-SiBCN) were fabricated, which significantly improved the sintering activity and oxidation performance. The effect of MA@PDCs-SiBCN structure on oxidation behaviors and kinetics of oxide layer growth of the SiBCN ceramics at 1500 degrees C was investigated, indicating that the significantly improved oxidation resistance is attributed to the different heterogeneous oxidation behaviors, especially in the initial stage. Therefore, the heterogeneous oxidation behaviors and kinetic laws of different phases in MA@PDCs-SiBCN ceramics at different temperature ranges and their effects on structural evolution and oxide layer composition were analyzed by comparison with the MA-SiBCN ceramics. The significantly improved oxidation resistance of MA@PDCsSiBCN ceramics should be attributed to the inhibition of MA@PDCs-SiBCN structure to heterogeneous oxidation, especially the consumption of t-C, and different oxide layer composition generated from microcrystalline structure rather than nanocapsule-like crystalline structure.

Freie Schlagworte: SiBCN ceramics,MA@PDCs-SiBCN structure, Oxidation, Kinetics analysis
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Werkstofftechnik und Ressourcenmanagement
Hinterlegungsdatum: 17 Jan 2025 09:42
Letzte Änderung: 17 Jan 2025 09:42
PPN: 525395385
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