Nasemann, Sina ; Franz, Roman ; Kargin, Denis ; Bruhn, Clemens ; Kelemen, Zsolt ; Gutmann, Torsten ; Pietschnig, Rudolf (2024)
At the limits of bisphosphonio‐substituted stannylenes.
In: Chemistry – An Asian Journal, 19 (8)
doi: 10.1002/asia.202300950
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
Donor stabilization of Sn(II) and Pb(II) halides with 1,1’‐ferrocenylene bridged bisphosphanes has been explored for Fe(C 5 H 4 P(C 6 H 5 ) 2 ) 2 (dppf), and Fe(C 5 H 4 PH(C 4 H 9 )) 2 . These bisphosphanes are reacted with SnBr 2 and PbCl 2 with and without additional Lewis acid (AlCl 3) forming acyclic and cyclic donor adducts from which the latter represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed, characterization includes solution and solid‐state NMR in addition to SC‐XRD, amended by DFT calculations.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Nasemann, Sina ; Franz, Roman ; Kargin, Denis ; Bruhn, Clemens ; Kelemen, Zsolt ; Gutmann, Torsten ; Pietschnig, Rudolf |
| Art des Eintrags: | Bibliographie |
| Titel: | At the limits of bisphosphonio‐substituted stannylenes |
| Sprache: | Englisch |
| Publikationsjahr: | 16 April 2024 |
| Verlag: | Wiley-VCH |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Chemistry – An Asian Journal |
| Jahrgang/Volume einer Zeitschrift: | 19 |
| (Heft-)Nummer: | 8 |
| DOI: | 10.1002/asia.202300950 |
| Kurzbeschreibung (Abstract): | Donor stabilization of Sn(II) and Pb(II) halides with 1,1’‐ferrocenylene bridged bisphosphanes has been explored for Fe(C 5 H 4 P(C 6 H 5 ) 2 ) 2 (dppf), and Fe(C 5 H 4 PH(C 4 H 9 )) 2 . These bisphosphanes are reacted with SnBr 2 and PbCl 2 with and without additional Lewis acid (AlCl 3) forming acyclic and cyclic donor adducts from which the latter represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed, characterization includes solution and solid‐state NMR in addition to SC‐XRD, amended by DFT calculations. |
| ID-Nummer: | Artikel-ID: e202300950 |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Physikalische Chemie |
| Hinterlegungsdatum: | 13 Jan 2025 10:15 |
| Letzte Änderung: | 14 Jan 2025 06:31 |
| PPN: | 525305270 |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
 |
Frage zum Eintrag |
Optionen (nur für Redakteure)
 |
Redaktionelle Details anzeigen |
Drucken
Impressum