Sheng, Huiying ; Graczyk‐Zajac, Magdalena ; Tian, Honghong ; Qu, Fangmu ; Zhang, Yaohao ; Dürrschnabel, Michael ; Weidenkaff, Anke ; Riedel, Ralf (2024)
Harnessing regenerated graphite from spent lithium‐ion batteries to enhance the performance of sulfur cathode in lithium‐sulfur batteries.
In: Batteries & Supercaps, 7 (6)
doi: 10.1002/batt.202400003
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
In this work, a facile hydrometallurgical approach combined with heat treatment has been adopted to recycle spent graphite from retired lithium‐ion battery cells. Graphite regenerated with 18 M H 2 SO 4 leaching leads to a high specific surface area, significant porosity and small crystallite size. The regenerated graphite has been infiltrated with sulfur under solvothermal conditions at 160 °C. The sample containing 68 wt % of sulfur recovers a capacity of 224 mAh/g after 100 cycles. Furthermore, the electrode with a higher sulfur content of 84 wt %, recuperates the specific discharging capacity of 207 mAh/g after 100 cycles. After the initial fading during the first 5–10 cycles, the cathodes based on regenerated graphite demonstrate stable cycling behavior. This research not only offers an accessible and scalable method for regenerating graphite from spent LIBs but also demonstrates a new application of the regenerated graphite in LSBs, showcasing outstanding electrochemical performance.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Sheng, Huiying ; Graczyk‐Zajac, Magdalena ; Tian, Honghong ; Qu, Fangmu ; Zhang, Yaohao ; Dürrschnabel, Michael ; Weidenkaff, Anke ; Riedel, Ralf |
| Art des Eintrags: | Bibliographie |
| Titel: | Harnessing regenerated graphite from spent lithium‐ion batteries to enhance the performance of sulfur cathode in lithium‐sulfur batteries |
| Sprache: | Englisch |
| Publikationsjahr: | Juni 2024 |
| Ort: | Weinheim |
| Verlag: | Wiley-VCH |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Batteries & Supercaps |
| Jahrgang/Volume einer Zeitschrift: | 7 |
| (Heft-)Nummer: | 6 |
| DOI: | 10.1002/batt.202400003 |
| Kurzbeschreibung (Abstract): | In this work, a facile hydrometallurgical approach combined with heat treatment has been adopted to recycle spent graphite from retired lithium‐ion battery cells. Graphite regenerated with 18 M H 2 SO 4 leaching leads to a high specific surface area, significant porosity and small crystallite size. The regenerated graphite has been infiltrated with sulfur under solvothermal conditions at 160 °C. The sample containing 68 wt % of sulfur recovers a capacity of 224 mAh/g after 100 cycles. Furthermore, the electrode with a higher sulfur content of 84 wt %, recuperates the specific discharging capacity of 207 mAh/g after 100 cycles. After the initial fading during the first 5–10 cycles, the cathodes based on regenerated graphite demonstrate stable cycling behavior. This research not only offers an accessible and scalable method for regenerating graphite from spent LIBs but also demonstrates a new application of the regenerated graphite in LSBs, showcasing outstanding electrochemical performance. |
| Freie Schlagworte: | spent graphite, recycling, hydrometallurgy, lithium sulfur battery |
| ID-Nummer: | Artikel-ID: e202400003 |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Werkstofftechnik und Ressourcenmanagement |
| Hinterlegungsdatum: | 08 Jan 2025 09:16 |
| Letzte Änderung: | 08 Jan 2025 13:00 |
| PPN: | 52512277X |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
 |
Frage zum Eintrag |
Optionen (nur für Redakteure)
 |
Redaktionelle Details anzeigen |
Drucken
Impressum