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Accessibility of fiber surface sites for polymeric additives determines dry and wet tensile strength of paper sheets

Schäfer, J.-L. ; Schölch, S. ; Prucker, O. ; Brandstetter, T. ; Rühe, J. ; Stockert, A. Ritter v. ; Meckel, T. ; Biesalski, M. (2021)
Accessibility of fiber surface sites for polymeric additives determines dry and wet tensile strength of paper sheets.
In: Cellulose, 28 (9)
doi: 10.1007/s10570-021-03817-7
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

This contribution focuses on understanding of paper wet-strength properties, by taking a closer look at the spatial distribution of wet-strengthening polymers inside the cellulosic fiber network deposited under different treatment conditions using confocal laser scanning microscopy as in situ imaging tool. We compare the behavior of paper samples treated with a photochemically cross-linkable copolymer using an impregnation process employing three different solvents, namely water, 2-propanol (IPA) and 1-butanol (BuOH), respectively. As these solvents swell paper fibers to quite different extents, the deposition of the polymer, on, in or in-between the cellulosic fibers varies quite strongly, as is shown by in-depth analysis using confocal laser scanning microscopy. The difference in accessibility of distinct surface sites exclusively on or also in and between the fibers controls the macroscopic tensile strength under both dry and wet conditions.

Typ des Eintrags: Artikel
Erschienen: 2021
Autor(en): Schäfer, J.-L. ; Schölch, S. ; Prucker, O. ; Brandstetter, T. ; Rühe, J. ; Stockert, A. Ritter v. ; Meckel, T. ; Biesalski, M.
Art des Eintrags: Bibliographie
Titel: Accessibility of fiber surface sites for polymeric additives determines dry and wet tensile strength of paper sheets
Sprache: Englisch
Publikationsjahr: Juni 2021
Ort: Dordrecht
Verlag: Springer Science
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Cellulose
Jahrgang/Volume einer Zeitschrift: 28
(Heft-)Nummer: 9
DOI: 10.1007/s10570-021-03817-7
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Kurzbeschreibung (Abstract):

This contribution focuses on understanding of paper wet-strength properties, by taking a closer look at the spatial distribution of wet-strengthening polymers inside the cellulosic fiber network deposited under different treatment conditions using confocal laser scanning microscopy as in situ imaging tool. We compare the behavior of paper samples treated with a photochemically cross-linkable copolymer using an impregnation process employing three different solvents, namely water, 2-propanol (IPA) and 1-butanol (BuOH), respectively. As these solvents swell paper fibers to quite different extents, the deposition of the polymer, on, in or in-between the cellulosic fibers varies quite strongly, as is shown by in-depth analysis using confocal laser scanning microscopy. The difference in accessibility of distinct surface sites exclusively on or also in and between the fibers controls the macroscopic tensile strength under both dry and wet conditions.

Freie Schlagworte: Cellulose, Paper, Wet strength, Spatial distribution, Swelling, Photo-crosslinking
Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 540 Chemie
Fachbereich(e)/-gebiet(e): 07 Fachbereich Chemie
07 Fachbereich Chemie > Ernst-Berl-Institut
07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie
07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie > Makromolekulare Chemie und Papierchemie
Hinterlegungsdatum: 11 Dez 2024 07:48
Letzte Änderung: 11 Dez 2024 07:48
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