Lin, Ling ; Wang, Kai ; Azmi, Raheleh ; Wang, Junbo ; Sarkar, Abhishek ; Botros, Miriam ; Najib, Saleem ; Cui, Yanyan ; Stenzel, David ; Anitha Sukkurji, Parvathy ; Wang, Qingsong ; Hahn, Horst ; Schweidler, Simon ; Breitung, Ben (2020)
Mechanochemical synthesis: route to novel rock-salt-structured high-entropy oxides and oxyfluorides.
In: Journal of Materials Science, 55 (36)
doi: 10.1007/s10853-020-05183-4
Artikel, Bibliographie
Dies ist die neueste Version dieses Eintrags.
Kurzbeschreibung (Abstract)
A facile mechanochemical reaction at ambient temperature was successfully applied to synthesize novel single-phase rock-salt-structured high-entropy oxides, containing five, six and seven metal elements in equiatomic amounts. This synthesis approach overcomes the limitations of the commonly known synthesis procedures, which would result in multiple-phase compounds. Redox-sensitive elements, such as Fe²⁺ and Mn²⁺, can now be considered. The corresponding single-phase Li-containing high-entropy oxyfluorides were obtained by introducing LiF into the lattice using the same strategy. All materials show single-phase rock-salt structures with lattice parameters depending on the incorporated ion sizes. Solid solution states result in high configurational entropies, and all elements appear homogenously distributed over the whole cationic and anionic sublattice. The straightforward synthesis technique, combined with utilized simple binary oxide precursors, paves the way for a multitude of novel high-entropy oxide and oxyfluoride compounds. The compounds were studied by means of X-ray diffraction, transmission electron microscopy, energy-dispersive X-ray spectroscopy and Mössbauer spectroscopy.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2020 |
| Autor(en): | Lin, Ling ; Wang, Kai ; Azmi, Raheleh ; Wang, Junbo ; Sarkar, Abhishek ; Botros, Miriam ; Najib, Saleem ; Cui, Yanyan ; Stenzel, David ; Anitha Sukkurji, Parvathy ; Wang, Qingsong ; Hahn, Horst ; Schweidler, Simon ; Breitung, Ben |
| Art des Eintrags: | Bibliographie |
| Titel: | Mechanochemical synthesis: route to novel rock-salt-structured high-entropy oxides and oxyfluorides |
| Sprache: | Englisch |
| Publikationsjahr: | Dezember 2020 |
| Ort: | Dordrecht |
| Verlag: | Springer Science |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Journal of Materials Science |
| Jahrgang/Volume einer Zeitschrift: | 55 |
| (Heft-)Nummer: | 36 |
| DOI: | 10.1007/s10853-020-05183-4 |
| Zugehörige Links: | |
| Kurzbeschreibung (Abstract): | A facile mechanochemical reaction at ambient temperature was successfully applied to synthesize novel single-phase rock-salt-structured high-entropy oxides, containing five, six and seven metal elements in equiatomic amounts. This synthesis approach overcomes the limitations of the commonly known synthesis procedures, which would result in multiple-phase compounds. Redox-sensitive elements, such as Fe²⁺ and Mn²⁺, can now be considered. The corresponding single-phase Li-containing high-entropy oxyfluorides were obtained by introducing LiF into the lattice using the same strategy. All materials show single-phase rock-salt structures with lattice parameters depending on the incorporated ion sizes. Solid solution states result in high configurational entropies, and all elements appear homogenously distributed over the whole cationic and anionic sublattice. The straightforward synthesis technique, combined with utilized simple binary oxide precursors, paves the way for a multitude of novel high-entropy oxide and oxyfluoride compounds. The compounds were studied by means of X-ray diffraction, transmission electron microscopy, energy-dispersive X-ray spectroscopy and Mössbauer spectroscopy. |
| Freie Schlagworte: | Materials Science, general, Characterization and Evaluation of Materials, Polymer Sciences, Solid Mechanics, Crystallography and Scattering Methods, Classical Mechanics |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 600 Technik, Medizin, angewandte Wissenschaften > 660 Technische Chemie |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Mechanik Funktionaler Materialien 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Gemeinschaftslabor Nanomaterialien |
| Hinterlegungsdatum: | 11 Dez 2024 07:18 |
| Letzte Änderung: | 11 Dez 2024 07:18 |
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| Suche nach Titel in: | TUfind oder in Google |
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Mechanochemical synthesis: route to novel rock-salt-structured high-entropy oxides and oxyfluorides. (deposited 10 Dez 2024 13:23)
- Mechanochemical synthesis: route to novel rock-salt-structured high-entropy oxides and oxyfluorides. (deposited 11 Dez 2024 07:18) [Gegenwärtig angezeigt]
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