Auernhammer, Julia ; Bell, Alena K. ; Schulze, Marcus ; Du, Yue ; Stühn, Lukas ; Wendenburg, Sonja ; Pause, Isabelle ; Biesalski, Markus ; Ensinger, Wolfgang ; Stark, Robert W. (2024)
Nanomechanical characterisation of a water-repelling terpolymer coating of cellulosic fibres.
In: Cellulose, 2021, 28 (4)
doi: 10.26083/tuprints-00023524
Artikel, Zweitveröffentlichung, Verlagsversion
 | Es ist eine neuere Version dieses Eintrags verfügbar. |
Kurzbeschreibung (Abstract)
Polymer coatings on cellulosic fibres are widely used to enhance the natural fibre properties by improving, for example, the hydrophobicity and wet strength. Here, we investigate the effects of a terpolymer P(S-co-MABP-co-PyMA) coating on cotton linters and eucalyptus fibres to improve the resistance of cellulose fibres against wetness. Coated and uncoated fibres were characterised by using scanning electron microscopy, contact angle measurements, Raman spectroscopy and atomic force microscopy with the objective of correlating macroscopic properties such as the hydrophobicity of the fleece with microscopic properties such as the coating distribution and local nanomechanics. The scanning electron and fluorescence microscopy results revealed the distribution of the coating on the paper fleeces and fibres. Contact angle measurements proved the hydrophobic character of the coated fleece, which was also confirmed by Raman spectroscopy measurements that investigated the water uptake in single fibres. The water uptake also induced a change in the local mechanical properties, as measured by atomic force microscopy. These results verify the basic functionality of the hydrophobic coating on fibres and paper fleeces but call into question the homogeneity of the coating.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Auernhammer, Julia ; Bell, Alena K. ; Schulze, Marcus ; Du, Yue ; Stühn, Lukas ; Wendenburg, Sonja ; Pause, Isabelle ; Biesalski, Markus ; Ensinger, Wolfgang ; Stark, Robert W. |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Nanomechanical characterisation of a water-repelling terpolymer coating of cellulosic fibres |
| Sprache: | Englisch |
| Publikationsjahr: | 10 Dezember 2024 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | März 2021 |
| Ort der Erstveröffentlichung: | Dordrecht |
| Verlag: | Springer Science |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Cellulose |
| Jahrgang/Volume einer Zeitschrift: | 28 |
| (Heft-)Nummer: | 4 |
| DOI: | 10.26083/tuprints-00023524 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/23524 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Polymer coatings on cellulosic fibres are widely used to enhance the natural fibre properties by improving, for example, the hydrophobicity and wet strength. Here, we investigate the effects of a terpolymer P(S-co-MABP-co-PyMA) coating on cotton linters and eucalyptus fibres to improve the resistance of cellulose fibres against wetness. Coated and uncoated fibres were characterised by using scanning electron microscopy, contact angle measurements, Raman spectroscopy and atomic force microscopy with the objective of correlating macroscopic properties such as the hydrophobicity of the fleece with microscopic properties such as the coating distribution and local nanomechanics. The scanning electron and fluorescence microscopy results revealed the distribution of the coating on the paper fleeces and fibres. Contact angle measurements proved the hydrophobic character of the coated fleece, which was also confirmed by Raman spectroscopy measurements that investigated the water uptake in single fibres. The water uptake also induced a change in the local mechanical properties, as measured by atomic force microscopy. These results verify the basic functionality of the hydrophobic coating on fibres and paper fleeces but call into question the homogeneity of the coating. |
| Freie Schlagworte: | Cellulose, Cotton linters, Eucalyptus, P(S-co-MABP-co-PyMA), Hydrophobicity, Scanning electron microscopy, Contact angle goniometry, Fluorescence microscopy, Raman spectroscopy, Atomic force microscopy |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-235243 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 530 Physik 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialanalytik 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Physics of Surfaces 07 Fachbereich Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie > Makromolekulare Chemie und Papierchemie |
| Hinterlegungsdatum: | 10 Dez 2024 13:14 |
| Letzte Änderung: | 11 Dez 2024 07:41 |
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| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
- Nanomechanical characterisation of a water-repelling terpolymer coating of cellulosic fibres. (deposited 10 Dez 2024 13:14) [Gegenwärtig angezeigt]
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