Gazenbiller, Eugen ; Arya, Visheet ; Reitz, Rüdiger ; Oechsner, Matthias ; Zheludkevich, Mikhail L. ; Höche, Daniel (2024)
Mechanistic insights into chemical corrosion of AA1050 in ethanol‐blended fuels with water contamination via phase field modeling.
In: Materials and Corrosion = Werkstoffe und Korrosion, 75 (9)
doi: 10.1002/maco.202414388
Artikel, Bibliographie
Dies ist die neueste Version dieses Eintrags.
Kurzbeschreibung (Abstract)
Aluminum alloys are widely used in automotive construction, and since the introduction of biogenic ethanol into fuels, the issue of nonaqueous alcoholate corrosion has become an important topic. In this paper, the kinetics of AA1050 temperature‐induced alcoholate pitting corrosion are examined experimentally with a specially constructed microreactor. The generated data are utilized to create a phase field model for the pit growth phase. The effects of ethanol‐blend composition and water content are quantitatively assessed and simulated. Phase field simulations allow for the first time the mechanistic characterization of the chemical corrosion process with a water content of up to 0.3% and an estimation of relevant reaction parameters at temperatures of up to 150°C. The approach can further be utilized to develop strategies for minimizing corrosion risk in‐service.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Gazenbiller, Eugen ; Arya, Visheet ; Reitz, Rüdiger ; Oechsner, Matthias ; Zheludkevich, Mikhail L. ; Höche, Daniel |
| Art des Eintrags: | Bibliographie |
| Titel: | Mechanistic insights into chemical corrosion of AA1050 in ethanol‐blended fuels with water contamination via phase field modeling |
| Sprache: | Englisch |
| Publikationsjahr: | September 2024 |
| Ort: | Weinheim |
| Verlag: | Wiley-VCH |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Materials and Corrosion = Werkstoffe und Korrosion |
| Jahrgang/Volume einer Zeitschrift: | 75 |
| (Heft-)Nummer: | 9 |
| DOI: | 10.1002/maco.202414388 |
| Zugehörige Links: | |
| Kurzbeschreibung (Abstract): | Aluminum alloys are widely used in automotive construction, and since the introduction of biogenic ethanol into fuels, the issue of nonaqueous alcoholate corrosion has become an important topic. In this paper, the kinetics of AA1050 temperature‐induced alcoholate pitting corrosion are examined experimentally with a specially constructed microreactor. The generated data are utilized to create a phase field model for the pit growth phase. The effects of ethanol‐blend composition and water content are quantitatively assessed and simulated. Phase field simulations allow for the first time the mechanistic characterization of the chemical corrosion process with a water content of up to 0.3% and an estimation of relevant reaction parameters at temperatures of up to 150°C. The approach can further be utilized to develop strategies for minimizing corrosion risk in‐service. |
| Freie Schlagworte: | aluminum, finite element method, non‐aqueous corrosion, phase field model |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 600 Technik, Medizin, angewandte Wissenschaften > 620 Ingenieurwissenschaften und Maschinenbau 600 Technik, Medizin, angewandte Wissenschaften > 670 Industrielle und handwerkliche Fertigung |
| Fachbereich(e)/-gebiet(e): | 16 Fachbereich Maschinenbau 16 Fachbereich Maschinenbau > Fachgebiet und Institut für Werkstoffkunde - Zentrum für Konstruktionswerkstoffe - Staatliche Materialprüfungsanstalt Darmstadt (IfW-MPA) |
| Hinterlegungsdatum: | 28 Nov 2024 06:17 |
| Letzte Änderung: | 28 Nov 2024 07:06 |
| PPN: | 524192812 |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
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Mechanistic insights into chemical corrosion of AA1050 in ethanol‐blended fuels with water contamination via phase field modeling. (deposited 27 Nov 2024 12:42)
- Mechanistic insights into chemical corrosion of AA1050 in ethanol‐blended fuels with water contamination via phase field modeling. (deposited 28 Nov 2024 06:17) [Gegenwärtig angezeigt]
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