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Single‐source precursor synthesis of a compositionally complex early transitional metal carbonitride (Ti,Zr,Hf,Nb,Ta)NₓC₁₋ₓ

Teppala, Dharma Teja ; Bernauer, Jan ; Rashid, Aasir ; Pejic, Milan ; Zagorac, Dejan ; Matovic, Branko ; Ionescu, Emanuel (2024)
Single‐source precursor synthesis of a compositionally complex early transitional metal carbonitride (Ti,Zr,Hf,Nb,Ta)NₓC₁₋ₓ.
In: Advanced Engineering Materials, 26 (18)
doi: 10.1002/adem.202302165
Artikel, Bibliographie

Dies ist die neueste Version dieses Eintrags.

Kurzbeschreibung (Abstract)

Compositionally complex transitional metal nitrides are possible candidates for ultra‐high temperature usage and are known for their superior properties due to the high configuration entropy. It is often difficult to synthesize pure metal nitrides in bulk, due to significant oxygen contamination; hence, they are synthesized mainly as thin films through magnetron sputtering, chemical vapor deposition or surface nitridation of high entropy alloys. The present article reports on a single‐phase compositionally complex ceramic, i.e., (Ti₀.₂Zr₀.₂Hf₀.₂Nb₀.₂Ta₀.₂)NₓC₁₋ₓ, that is synthesized for the first time by employing an organometallic precursor route and using a double ammonolysis process. A multidisciplinary approach is performed to study these compositionally complex nitride and carbonitride systems, including experimental and theoretical investigations.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Teppala, Dharma Teja ; Bernauer, Jan ; Rashid, Aasir ; Pejic, Milan ; Zagorac, Dejan ; Matovic, Branko ; Ionescu, Emanuel
Art des Eintrags: Bibliographie
Titel: Single‐source precursor synthesis of a compositionally complex early transitional metal carbonitride (Ti,Zr,Hf,Nb,Ta)NₓC₁₋ₓ
Sprache: Englisch
Publikationsjahr: September 2024
Ort: Weinheim
Verlag: Wiley-VCH
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Advanced Engineering Materials
Jahrgang/Volume einer Zeitschrift: 26
(Heft-)Nummer: 18
Kollation: 10 Seiten
DOI: 10.1002/adem.202302165
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Kurzbeschreibung (Abstract):

Compositionally complex transitional metal nitrides are possible candidates for ultra‐high temperature usage and are known for their superior properties due to the high configuration entropy. It is often difficult to synthesize pure metal nitrides in bulk, due to significant oxygen contamination; hence, they are synthesized mainly as thin films through magnetron sputtering, chemical vapor deposition or surface nitridation of high entropy alloys. The present article reports on a single‐phase compositionally complex ceramic, i.e., (Ti₀.₂Zr₀.₂Hf₀.₂Nb₀.₂Ta₀.₂)NₓC₁₋ₓ, that is synthesized for the first time by employing an organometallic precursor route and using a double ammonolysis process. A multidisciplinary approach is performed to study these compositionally complex nitride and carbonitride systems, including experimental and theoretical investigations.

Freie Schlagworte: ammonolysis, compositional complexity, DFT, modeling, nitrides
ID-Nummer: Artikel-ID: 2302165
Zusätzliche Informationen:

Special Issue: Dedicated to Nahum Travitzky

Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 530 Physik
600 Technik, Medizin, angewandte Wissenschaften > 660 Technische Chemie
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Werkstofftechnik und Ressourcenmanagement
Hinterlegungsdatum: 06 Nov 2024 09:35
Letzte Änderung: 06 Nov 2024 10:40
PPN: 523221355
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