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Damage-tolerant oxides by imprint of an ultra-high dislocation density

Preuß, Oliver ; Bruder, Enrico ; Zhang, Jiawen ; Lu, Wenjun ; Rödel, Jürgen ; Fang, Xufei (2025)
Damage-tolerant oxides by imprint of an ultra-high dislocation density.
In: Journal of the European Ceramic Society, 45 (2)
doi: 10.1016/j.jeurceramsoc.2024.116969
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Dislocations in ductile ceramics offer the potential for robust mechanical performance while unlocking versatile functional properties. Previous studies have been limited by small volumes with dislocations and/or low dislocation densities in ceramics. Here, we use Brinell ball scratching to create crack-free, large plastic zones, offering a simple and effective method for dislocation engineering at room temperature. Using MgO, we tailor high dislocation densities up to ~1015 m 2. We characterise the plastic zones by chemical etching, electron channelling contrast imaging, and scanning transmission electron microscopy, and further demonstrate that crack initiation and propagation in the plastic zones with high-density dislocations can be completely suppressed. The residual stresses in the plastic zones were analysed using high-resolution electron backscatter diffraction. With the residual stress being subsequently relieved via thermal annealing while retaining the high-density dislocations, we observe the cracks are no longer completely suppressed, but the pure toughening effect of the dislocations remains evident.

Typ des Eintrags: Artikel
Erschienen: 2025
Autor(en): Preuß, Oliver ; Bruder, Enrico ; Zhang, Jiawen ; Lu, Wenjun ; Rödel, Jürgen ; Fang, Xufei
Art des Eintrags: Bibliographie
Titel: Damage-tolerant oxides by imprint of an ultra-high dislocation density
Sprache: Englisch
Publikationsjahr: Februar 2025
Verlag: Elsevier
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the European Ceramic Society
Jahrgang/Volume einer Zeitschrift: 45
(Heft-)Nummer: 2
DOI: 10.1016/j.jeurceramsoc.2024.116969
Kurzbeschreibung (Abstract):

Dislocations in ductile ceramics offer the potential for robust mechanical performance while unlocking versatile functional properties. Previous studies have been limited by small volumes with dislocations and/or low dislocation densities in ceramics. Here, we use Brinell ball scratching to create crack-free, large plastic zones, offering a simple and effective method for dislocation engineering at room temperature. Using MgO, we tailor high dislocation densities up to ~1015 m 2. We characterise the plastic zones by chemical etching, electron channelling contrast imaging, and scanning transmission electron microscopy, and further demonstrate that crack initiation and propagation in the plastic zones with high-density dislocations can be completely suppressed. The residual stresses in the plastic zones were analysed using high-resolution electron backscatter diffraction. With the residual stress being subsequently relieved via thermal annealing while retaining the high-density dislocations, we observe the cracks are no longer completely suppressed, but the pure toughening effect of the dislocations remains evident.

Freie Schlagworte: dislocation, MgO, damage tolerance, fracture, room-temperature plasticity
ID-Nummer: Artikel-ID: 116969
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 10 Okt 2024 07:26
Letzte Änderung: 10 Okt 2024 12:13
PPN: 522089240
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