Khadke, Prashant ; Tichter, Tim ; Boettcher, Tim ; Muench, Falk ; Ensinger, Wolfgang ; Roth, Christina (2024)
A simple and effective method for the accurate extraction of kinetic parameters using differential Tafel plots.
In: Scientific Reports, 2021, 11 (1)
doi: 10.26083/tuprints-00023589
Artikel, Zweitveröffentlichung, Verlagsversion
 | Es ist eine neuere Version dieses Eintrags verfügbar. |
Kurzbeschreibung (Abstract)
Abstract
The practice of estimating the transfer coefficient (α) and the exchange current (i₀) by arbitrarily placing a straight line on Tafel plots has led to high variance in these parameters between different research groups. Generating Tafel plots by finding kinetic current, ik from the conventional mass transfer correction method does not guarantee an accurate estimation of the α and i₀. This is because a substantial difference in values of α and i₀ can arise from only minor deviations in the calculated values of ik. These minor deviations are often not easy to recognise in polarisation curves and Tafel plots. Recalling the IUPAC definition of α , the Tafel plots can be alternatively represented as differential Tafel plots (DTPs) by taking the first order differential of Tafel plots with respect to overpotential. Without further complex processing of the existing raw data, many crucial observations can be made from DTP which is otherwise very difficult to observe from Tafel plots. These for example include a) many perfectly looking experimental linear Tafel plots (R² > 0.999) can give rise to incorrect kinetic parameters b) substantial differences in values of α and i₀ can arise when the limiting current (iL) is just off by 5% while performing the mass transfer correction c) irrespective of the magnitude of the double layer charging current (ic), the Tafel plots can still get significantly skewed when the ratio of i₀/ic is small. Hence, in order to determine accurate values of α and i₀, we show how the DTP approach can be applied to experimental polarisation curves having well defined iL, poorly defined iL at all.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Khadke, Prashant ; Tichter, Tim ; Boettcher, Tim ; Muench, Falk ; Ensinger, Wolfgang ; Roth, Christina |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | A simple and effective method for the accurate extraction of kinetic parameters using differential Tafel plots |
| Sprache: | Englisch |
| Publikationsjahr: | 24 September 2024 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 26 April 2021 |
| Ort der Erstveröffentlichung: | London |
| Verlag: | Springer Nature |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Scientific Reports |
| Jahrgang/Volume einer Zeitschrift: | 11 |
| (Heft-)Nummer: | 1 |
| Kollation: | 15 Seiten |
| DOI: | 10.26083/tuprints-00023589 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/23589 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Abstract The practice of estimating the transfer coefficient (α) and the exchange current (i₀) by arbitrarily placing a straight line on Tafel plots has led to high variance in these parameters between different research groups. Generating Tafel plots by finding kinetic current, ik from the conventional mass transfer correction method does not guarantee an accurate estimation of the α and i₀. This is because a substantial difference in values of α and i₀ can arise from only minor deviations in the calculated values of ik. These minor deviations are often not easy to recognise in polarisation curves and Tafel plots. Recalling the IUPAC definition of α , the Tafel plots can be alternatively represented as differential Tafel plots (DTPs) by taking the first order differential of Tafel plots with respect to overpotential. Without further complex processing of the existing raw data, many crucial observations can be made from DTP which is otherwise very difficult to observe from Tafel plots. These for example include a) many perfectly looking experimental linear Tafel plots (R² > 0.999) can give rise to incorrect kinetic parameters b) substantial differences in values of α and i₀ can arise when the limiting current (iL) is just off by 5% while performing the mass transfer correction c) irrespective of the magnitude of the double layer charging current (ic), the Tafel plots can still get significantly skewed when the ratio of i₀/ic is small. Hence, in order to determine accurate values of α and i₀, we show how the DTP approach can be applied to experimental polarisation curves having well defined iL, poorly defined iL at all. |
| Freie Schlagworte: | Batteries, Corrosion, Electrocatalysis, Electrochemistry, Fuel cells, Metal–organic frameworks |
| ID-Nummer: | Artikel-ID: 8974 |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-235890 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 530 Physik 500 Naturwissenschaften und Mathematik > 540 Chemie 600 Technik, Medizin, angewandte Wissenschaften > 620 Ingenieurwissenschaften und Maschinenbau |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialanalytik |
| Hinterlegungsdatum: | 24 Sep 2024 11:08 |
| Letzte Änderung: | 25 Sep 2024 09:01 |
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| Suche nach Titel in: | TUfind oder in Google |
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- A simple and effective method for the accurate extraction of kinetic parameters using differential Tafel plots. (deposited 24 Sep 2024 11:08) [Gegenwärtig angezeigt]
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