Buntkowsky, Gerd ; Döller, Sonja ; Haro-Mares, Nadia ; Gutmann, Torsten ; Hoffmann, Markus (2022)
Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica.
In: Zeitschrift für Physikalische Chemie, 236 (6-8)
doi: 10.1515/zpch-2021-3132
Artikel, Bibliographie
Dies ist die neueste Version dieses Eintrags.
Kurzbeschreibung (Abstract)
This review gives an overview of current trends in the investigation of confined molecules such as higher alcohols, ethylene glycol and polyethylene glycol as guest molecules in neat and functionalized mesoporous silica materials. All these molecules have both hydrophobic and hydrophilic parts. They are characteristic role-models for the investigation of confined surfactants. Their properties are studied by a combination of solid-state NMR and relaxometry with other physicochemical techniques and molecular dynamics techniques. It is shown that this combination delivers unique insights into the structure, arrangement, dynamical properties and the guest-host interactions inside the confinement.
Typ des Eintrags: | Artikel |
---|---|
Erschienen: | 2022 |
Autor(en): | Buntkowsky, Gerd ; Döller, Sonja ; Haro-Mares, Nadia ; Gutmann, Torsten ; Hoffmann, Markus |
Art des Eintrags: | Bibliographie |
Titel: | Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica |
Sprache: | Englisch |
Publikationsjahr: | 2022 |
Ort: | Darmstadt |
Verlag: | De Gruyter |
Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Zeitschrift für Physikalische Chemie |
Jahrgang/Volume einer Zeitschrift: | 236 |
(Heft-)Nummer: | 6-8 |
DOI: | 10.1515/zpch-2021-3132 |
Zugehörige Links: | |
Kurzbeschreibung (Abstract): | This review gives an overview of current trends in the investigation of confined molecules such as higher alcohols, ethylene glycol and polyethylene glycol as guest molecules in neat and functionalized mesoporous silica materials. All these molecules have both hydrophobic and hydrophilic parts. They are characteristic role-models for the investigation of confined surfactants. Their properties are studied by a combination of solid-state NMR and relaxometry with other physicochemical techniques and molecular dynamics techniques. It is shown that this combination delivers unique insights into the structure, arrangement, dynamical properties and the guest-host interactions inside the confinement. |
Freie Schlagworte: | confinement, dynamic nuclear polarization (DNP), green solvents, host-guest interactions, solid-state NMR, surfactants |
Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 530 Physik 500 Naturwissenschaften und Mathematik > 540 Chemie |
Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Physikalische Chemie |
Hinterlegungsdatum: | 02 Aug 2024 12:53 |
Letzte Änderung: | 02 Aug 2024 12:53 |
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Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica. (deposited 12 Jul 2023 13:05)
- Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica. (deposited 02 Aug 2024 12:53) [Gegenwärtig angezeigt]
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