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Fulvenes as Isomers of Benzenoid Compounds

Hafner, Klaus ; Häfner, K. H. ; König, C. ; Kreuder, M. ; Ploss, G. ; Schulz, G. ; Sturm, E. ; Völpel, K. H. (1963)
Fulvenes as Isomers of Benzenoid Compounds.
In: Angewandte Chemie International Edition, 2 (3)
doi: 10.1002/anie.196301231
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

With regard to the nature of their bonding and reactivity, fulvenes occupy a position intermediate between their benzenoid isomers and the olefins. The chemical and physical behavior of the fulvenes is determined either by the diene character of the cross-conjugated system or by the cylic conjugation in the five-membered ring, depending on the type of substituent at the exocyclic carbon atom. In addtion to several new substitution reactions, a description is given of the syntheses and reactions of 6-amino- and 6-hydroxyfulvenes, isomeric with anilines and phenols, the derivatives of which can be used for the preparation of new types of nonbenzenoid cyclic conjugated systems such as carbocyclic and heterocyclic azulenes, pseudoazulenes, thiepines, dihydropyridazines, and s-indacene.

Typ des Eintrags: Artikel
Erschienen: 1963
Autor(en): Hafner, Klaus ; Häfner, K. H. ; König, C. ; Kreuder, M. ; Ploss, G. ; Schulz, G. ; Sturm, E. ; Völpel, K. H.
Art des Eintrags: Bibliographie
Titel: Fulvenes as Isomers of Benzenoid Compounds
Sprache: Englisch
Publikationsjahr: 1963
Ort: Darmstadt
Verlag: Wiley
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Angewandte Chemie International Edition
Jahrgang/Volume einer Zeitschrift: 2
(Heft-)Nummer: 3
DOI: 10.1002/anie.196301231
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Kurzbeschreibung (Abstract):

With regard to the nature of their bonding and reactivity, fulvenes occupy a position intermediate between their benzenoid isomers and the olefins. The chemical and physical behavior of the fulvenes is determined either by the diene character of the cross-conjugated system or by the cylic conjugation in the five-membered ring, depending on the type of substituent at the exocyclic carbon atom. In addtion to several new substitution reactions, a description is given of the syntheses and reactions of 6-amino- and 6-hydroxyfulvenes, isomeric with anilines and phenols, the derivatives of which can be used for the preparation of new types of nonbenzenoid cyclic conjugated systems such as carbocyclic and heterocyclic azulenes, pseudoazulenes, thiepines, dihydropyridazines, and s-indacene.

Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 540 Chemie
Fachbereich(e)/-gebiet(e): 07 Fachbereich Chemie
07 Fachbereich Chemie > Clemens-Schöpf-Institut
07 Fachbereich Chemie > Clemens-Schöpf-Institut > Fachgebiet Organische Chemie
Hinterlegungsdatum: 02 Aug 2024 12:47
Letzte Änderung: 02 Aug 2024 12:47
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