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Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions

Brodrecht, Martin ; Kumari, Bharti ; Breitzke, Hergen ; Gutmann, Torsten ; Buntkowsky, Gerd (2018)
Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions.
In: Zeitschrift für Physikalische Chemie, 232 (7-8)
doi: 10.1515/zpch-2017-1059
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

A series of novel functionalized mesoporous silica-based materials with well-defined pore diameters, surface functionalization and surface morphology is synthesized by co-condensation or grafting techniques and characterized by solid-state NMR spectroscopy, DNP enhanced solid state-NMR and thermodynamic techniques. These materials are employed as host-systems for small-guest molecules like water, small alcohols, carbonic acids, small aromatic molecules, binary mixtures and others. The phase-behavior of these confined guests is studied by combinations of one dimensional solid-state NMR techniques (¹HMAS, ²H-line shape analysis, ¹³C CPMAS) and two-dimensional correlation experiments like ¹H-²⁹Si- solid-state HETCOR.

Typ des Eintrags: Artikel
Erschienen: 2018
Autor(en): Brodrecht, Martin ; Kumari, Bharti ; Breitzke, Hergen ; Gutmann, Torsten ; Buntkowsky, Gerd
Art des Eintrags: Bibliographie
Titel: Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions
Sprache: Englisch
Publikationsjahr: 2018
Verlag: De Gruyter
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Zeitschrift für Physikalische Chemie
Jahrgang/Volume einer Zeitschrift: 232
(Heft-)Nummer: 7-8
DOI: 10.1515/zpch-2017-1059
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Kurzbeschreibung (Abstract):

A series of novel functionalized mesoporous silica-based materials with well-defined pore diameters, surface functionalization and surface morphology is synthesized by co-condensation or grafting techniques and characterized by solid-state NMR spectroscopy, DNP enhanced solid state-NMR and thermodynamic techniques. These materials are employed as host-systems for small-guest molecules like water, small alcohols, carbonic acids, small aromatic molecules, binary mixtures and others. The phase-behavior of these confined guests is studied by combinations of one dimensional solid-state NMR techniques (¹HMAS, ²H-line shape analysis, ¹³C CPMAS) and two-dimensional correlation experiments like ¹H-²⁹Si- solid-state HETCOR.

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Keywords: confinement; micro-phase separation; solid-state-NMR

Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 540 Chemie
Fachbereich(e)/-gebiet(e): 07 Fachbereich Chemie
07 Fachbereich Chemie > Eduard Zintl-Institut
07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Physikalische Chemie
Hinterlegungsdatum: 02 Aug 2024 12:37
Letzte Änderung: 02 Aug 2024 12:37
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