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Near-surface plastic deformation in polycrystalline SrTiO3 via room-temperature cyclic Brinell indentation

Okafor, Chukwudalu ; Ding, Kuan ; Preuß, Oliver ; Khansur, Neamul H. ; Rheinheimer, Wolfgang ; Fang, Xufei (2024)
Near-surface plastic deformation in polycrystalline SrTiO3 via room-temperature cyclic Brinell indentation.
In: Journal of the American Ceramic Society, 107 (10)
doi: 10.1111/jace.19962
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

Dislocations are being used to tune versatile mechanical and functional prop- erties in oxides with most current studies focusing on single crystals. For potentially wider applications, polycrystalline ceramics are of concern, pro- vided that dislocations can be successfully introduced. However, in addition to preexisting pores and flaws, a major barrier for bulk plastic deformation of polycrystalline ceramics lies in the grain boundaries (GBs), which can lead to dislocation pile-up and cracking at the GBs due to the lack of sufficient indepen- dent slip systems in ceramics at room temperature. Here, we use the cyclic Brinell indentation method to circumvent the bulk deformation and focus on nearsurface regions to investigate the plastic deformation of polycrystalline SrTiO3 at room temperature. Dislocation etch-pit analysis suggests that plastic deformation can be initiated within the grains, at the GBs, and from the GB triple junction pores. The deformability of the individual grains is found to be dependent on the number of cycles, as also independently evidenced on single-crystal SrTiO3 with representative surface orientations (001), (011), and (111). We also identify a grain-size-dependent plastic deformation.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Okafor, Chukwudalu ; Ding, Kuan ; Preuß, Oliver ; Khansur, Neamul H. ; Rheinheimer, Wolfgang ; Fang, Xufei
Art des Eintrags: Bibliographie
Titel: Near-surface plastic deformation in polycrystalline SrTiO3 via room-temperature cyclic Brinell indentation
Sprache: Englisch
Publikationsjahr: 3 Juli 2024
Ort: Oxford
Verlag: Wiley Blackwell
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the American Ceramic Society
Jahrgang/Volume einer Zeitschrift: 107
(Heft-)Nummer: 10
DOI: 10.1111/jace.19962
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Kurzbeschreibung (Abstract):

Dislocations are being used to tune versatile mechanical and functional prop- erties in oxides with most current studies focusing on single crystals. For potentially wider applications, polycrystalline ceramics are of concern, pro- vided that dislocations can be successfully introduced. However, in addition to preexisting pores and flaws, a major barrier for bulk plastic deformation of polycrystalline ceramics lies in the grain boundaries (GBs), which can lead to dislocation pile-up and cracking at the GBs due to the lack of sufficient indepen- dent slip systems in ceramics at room temperature. Here, we use the cyclic Brinell indentation method to circumvent the bulk deformation and focus on nearsurface regions to investigate the plastic deformation of polycrystalline SrTiO3 at room temperature. Dislocation etch-pit analysis suggests that plastic deformation can be initiated within the grains, at the GBs, and from the GB triple junction pores. The deformability of the individual grains is found to be dependent on the number of cycles, as also independently evidenced on single-crystal SrTiO3 with representative surface orientations (001), (011), and (111). We also identify a grain-size-dependent plastic deformation.

Freie Schlagworte: cyclic indentation, dislocation, plasticity, strontium titanate, surface deformation
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 04 Jul 2024 11:29
Letzte Änderung: 20 Nov 2024 11:02
PPN: 519579518
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