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Microfluidic crystallization of surfactant-free doped zinc sulfide nanoparticles for optical bioimaging applications

Tajoli, Francesca ; Dengo, Nicola ; Mognato, Maddalena ; Dolcet, Paolo ; Lucchini, Giacomo ; Faresin, Andrea ; Grunwaldt, Jan-Dierk ; Huang, Xiaohui ; Badocco, Denis ; Maggini, Michele ; Kübel, Christian ; Speghini, Adolfo ; Carofiglio, Tommaso ; Gross, Silvia (2020)
Microfluidic crystallization of surfactant-free doped zinc sulfide nanoparticles for optical bioimaging applications.
In: ACS Applied Materials & Interfaces, 12 (39)
doi: 10.1021/acsami.0c13150
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The room-temperature controlled crystallization of monodispersed ZnS nanoparticles (average size of 5 nm) doped with luminescent ions (such as Mn2+, Eu3+, Sm3+, Nd3+, and Yb3+) was achieved via a microfluidic approach. The preparation did not require any stabilizing ligands or surfactants, minimizing potential sources of impurities. The synthesized nanomaterials were characterized from a structural (XRD and XAS at lanthanide L-3 edges), morphological (TEM), and compositional (XPS, ICP-MS) perspective, giving complementary information on the materials' features. In view of potential applications in the field of optical bioimaging, the optical emission properties of the doped nano-particles were assessed, and samples showed strong luminescent properties while being less affected by self-quenching mechanisms. Furthermore, in vitro cytotoxicity experiments were conducted, showing no negative effects and evidencing the appeal of the synthesized materials for potential applications in the field of optical bioimaging.

Typ des Eintrags: Artikel
Erschienen: 2020
Autor(en): Tajoli, Francesca ; Dengo, Nicola ; Mognato, Maddalena ; Dolcet, Paolo ; Lucchini, Giacomo ; Faresin, Andrea ; Grunwaldt, Jan-Dierk ; Huang, Xiaohui ; Badocco, Denis ; Maggini, Michele ; Kübel, Christian ; Speghini, Adolfo ; Carofiglio, Tommaso ; Gross, Silvia
Art des Eintrags: Bibliographie
Titel: Microfluidic crystallization of surfactant-free doped zinc sulfide nanoparticles for optical bioimaging applications
Sprache: Englisch
Publikationsjahr: 30 September 2020
Verlag: ACS Publications
Titel der Zeitschrift, Zeitung oder Schriftenreihe: ACS Applied Materials & Interfaces
Jahrgang/Volume einer Zeitschrift: 12
(Heft-)Nummer: 39
DOI: 10.1021/acsami.0c13150
Kurzbeschreibung (Abstract):

The room-temperature controlled crystallization of monodispersed ZnS nanoparticles (average size of 5 nm) doped with luminescent ions (such as Mn2+, Eu3+, Sm3+, Nd3+, and Yb3+) was achieved via a microfluidic approach. The preparation did not require any stabilizing ligands or surfactants, minimizing potential sources of impurities. The synthesized nanomaterials were characterized from a structural (XRD and XAS at lanthanide L-3 edges), morphological (TEM), and compositional (XPS, ICP-MS) perspective, giving complementary information on the materials' features. In view of potential applications in the field of optical bioimaging, the optical emission properties of the doped nano-particles were assessed, and samples showed strong luminescent properties while being less affected by self-quenching mechanisms. Furthermore, in vitro cytotoxicity experiments were conducted, showing no negative effects and evidencing the appeal of the synthesized materials for potential applications in the field of optical bioimaging.

Freie Schlagworte: ZnS, zinc sulfide, microfluidics, optical bioimaging, doping, luminescence, NIR emission
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > In-Situ Elektronenmikroskopie
Hinterlegungsdatum: 12 Jun 2024 07:59
Letzte Änderung: 12 Jun 2024 07:59
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