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Anisotropic grain boundary diffusion process in textured sintered and hot-deformed Nd-Fe-B magnets

Helbig, Tim ; Abel, Andreas ; Sawatzki, Simon ; Gröb, Thorsten ; Dirba, Imants ; Ener, Semih ; Gutfleisch, Oliver (2024)
Anisotropic grain boundary diffusion process in textured sintered and hot-deformed Nd-Fe-B magnets.
In: Journal of Alloys and Compounds
doi: 10.1016/j.jallcom.2024.174490
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

A systematic study of the dependence of the Grain Boundary Diffusion Process (GBDP) on texture using Dy and Dy-Nd-Cu in microcrystalline sintered and nanocrystalline hot deformed Nd-Fe-B magnets was performed. Diffusion parallel or perpendicular to the texture direction, the nominal c-axes orientation in the polycrystals, was investigated. By measuring thin slices from the respective samples, coercivity as a function of (i) magnet thickness and (ii) diffusion depth was obtained showing that GBDP efficiency depends on the diffusion direction, diffusion source as well as the grain morphology originating from the magnet production route. In nanocrystalline hot deformed magnets perpendicular diffusion is superior due to the platelet-like shape of the grains. Microcrystalline sintered magnets consist of equiaxed grains hence the main effects originate in anisotropic lattice diffusion and pole surface hardening. The magnetic properties are correlated with a comprehensive analysis of microstructure, chemistry and magnetization reversal.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Helbig, Tim ; Abel, Andreas ; Sawatzki, Simon ; Gröb, Thorsten ; Dirba, Imants ; Ener, Semih ; Gutfleisch, Oliver
Art des Eintrags: Bibliographie
Titel: Anisotropic grain boundary diffusion process in textured sintered and hot-deformed Nd-Fe-B magnets
Sprache: Englisch
Publikationsjahr: 18 April 2024
Verlag: Elsevier
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Alloys and Compounds
DOI: 10.1016/j.jallcom.2024.174490
Kurzbeschreibung (Abstract):

A systematic study of the dependence of the Grain Boundary Diffusion Process (GBDP) on texture using Dy and Dy-Nd-Cu in microcrystalline sintered and nanocrystalline hot deformed Nd-Fe-B magnets was performed. Diffusion parallel or perpendicular to the texture direction, the nominal c-axes orientation in the polycrystals, was investigated. By measuring thin slices from the respective samples, coercivity as a function of (i) magnet thickness and (ii) diffusion depth was obtained showing that GBDP efficiency depends on the diffusion direction, diffusion source as well as the grain morphology originating from the magnet production route. In nanocrystalline hot deformed magnets perpendicular diffusion is superior due to the platelet-like shape of the grains. Microcrystalline sintered magnets consist of equiaxed grains hence the main effects originate in anisotropic lattice diffusion and pole surface hardening. The magnetic properties are correlated with a comprehensive analysis of microstructure, chemistry and magnetization reversal.

Freie Schlagworte: Nd-Fe-B, grain boundary diffusion, coercivity
Zusätzliche Informationen:

Artikel-ID: 174490

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Funktionale Materialien
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Physikalische Metallkunde
Hinterlegungsdatum: 25 Apr 2024 06:44
Letzte Änderung: 25 Apr 2024 08:54
PPN: 517482827
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