Funk, S. ; Bonn, M. ; Denzler, D. N. ; Hess, Ch. ; Wolf, M. ; Ertl, G. (2024)
Desorption of CO from Ru(001) induced by near-infrared femtosecond laser pulses.
In: The Journal of Chemical Physics, 2000, 112 (22)
doi: 10.26083/tuprints-00026898
Artikel, Zweitveröffentlichung, Verlagsversion
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Kurzbeschreibung (Abstract)
Irradiation of a Ru(001) surface covered with CO using intense femtosecond laser pulses (800 nm, 130 fs) leads to desorption of CO with a nonlinear dependence of the yield on the absorbed fluence (100–380 J/m²). Two-pulse correlation measurements reveal a response time of 20 ps (FWHM). The lack of an isotope effect together with the strong rise of the phonon temperature (2500 K) and the specific electronic structure of the adsorbate–substrate system strongly indicate that coupling to phonons is dominant. The experimental findings can be well reproduced within a friction-coupled heat bath model. Yet, pronounced dynamical cooling in desorption, found in the fluence-dependence of the translational energy, and in a non-Arrhenius behavior of the desorption probability reflect pronounced deviations from thermal equilibrium during desorption taking place on such a short time scale.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Funk, S. ; Bonn, M. ; Denzler, D. N. ; Hess, Ch. ; Wolf, M. ; Ertl, G. |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Desorption of CO from Ru(001) induced by near-infrared femtosecond laser pulses |
| Sprache: | Englisch |
| Publikationsjahr: | 23 April 2024 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2000 |
| Ort der Erstveröffentlichung: | Melville, NY |
| Verlag: | AIP Publishing |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | The Journal of Chemical Physics |
| Jahrgang/Volume einer Zeitschrift: | 112 |
| (Heft-)Nummer: | 22 |
| DOI: | 10.26083/tuprints-00026898 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/26898 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichungsservice |
| Kurzbeschreibung (Abstract): | Irradiation of a Ru(001) surface covered with CO using intense femtosecond laser pulses (800 nm, 130 fs) leads to desorption of CO with a nonlinear dependence of the yield on the absorbed fluence (100–380 J/m²). Two-pulse correlation measurements reveal a response time of 20 ps (FWHM). The lack of an isotope effect together with the strong rise of the phonon temperature (2500 K) and the specific electronic structure of the adsorbate–substrate system strongly indicate that coupling to phonons is dominant. The experimental findings can be well reproduced within a friction-coupled heat bath model. Yet, pronounced dynamical cooling in desorption, found in the fluence-dependence of the translational energy, and in a non-Arrhenius behavior of the desorption probability reflect pronounced deviations from thermal equilibrium during desorption taking place on such a short time scale. |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-268987 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 530 Physik 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Hinterlegungsdatum: | 23 Apr 2024 08:30 |
| Letzte Änderung: | 24 Apr 2024 14:27 |
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- Desorption of CO from Ru(001) induced by near-infrared femtosecond laser pulses. (deposited 23 Apr 2024 08:30) [Gegenwärtig angezeigt]
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