Lee, Pui Lap Jacob ; Thangavel, Vigneshwaran ; Guery, Claude ; Trautmann, Christina ; Toimil-Molares, Maria Eugenia ; Morcrette, Mathieu (2024)
Etched ion-track membranes as tailored separators in Li–S batteries.
In: Nanotechnology, 2021, 32 (36)
doi: 10.26083/tuprints-00020481
Artikel, Zweitveröffentlichung, Verlagsversion
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Kurzbeschreibung (Abstract)
Lithium–sulfur (Li–S) batteries are considered a promising next generation alternative to lithium-ion batteries for energy storage systems due to its high energy density. However, several challenges, such as the polysulfide redox shuttle causing self-discharge of the battery, remain unresolved. In this paper, we explore the use of polymer etched ion-track membranes as separators in Li–S batteries to mitigate the redox shuttle effect. Compared to commercial separators, their unique advantages lie in their very narrow pore size distribution, and the possibility to tailor and optimize the density, geometry, and diameter of the nanopores in an independent manner. Various polyethylene terephthalate membranes with diameters between 22 and 198 nm and different porosities were successfully integrated into Li–S coin cells. The reported coulombic efficiency of up to 97% with minor reduction in capacity opens a pathway to potentially address the polysulfide redox shuttle in Li–S batteries using tailored membranes.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Lee, Pui Lap Jacob ; Thangavel, Vigneshwaran ; Guery, Claude ; Trautmann, Christina ; Toimil-Molares, Maria Eugenia ; Morcrette, Mathieu |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Etched ion-track membranes as tailored separators in Li–S batteries |
| Sprache: | Englisch |
| Publikationsjahr: | 25 März 2024 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2021 |
| Ort der Erstveröffentlichung: | Bristol |
| Verlag: | IOP Publishing |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Nanotechnology |
| Jahrgang/Volume einer Zeitschrift: | 32 |
| (Heft-)Nummer: | 36 |
| Kollation: | 9 Seiten |
| DOI: | 10.26083/tuprints-00020481 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/20481 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Lithium–sulfur (Li–S) batteries are considered a promising next generation alternative to lithium-ion batteries for energy storage systems due to its high energy density. However, several challenges, such as the polysulfide redox shuttle causing self-discharge of the battery, remain unresolved. In this paper, we explore the use of polymer etched ion-track membranes as separators in Li–S batteries to mitigate the redox shuttle effect. Compared to commercial separators, their unique advantages lie in their very narrow pore size distribution, and the possibility to tailor and optimize the density, geometry, and diameter of the nanopores in an independent manner. Various polyethylene terephthalate membranes with diameters between 22 and 198 nm and different porosities were successfully integrated into Li–S coin cells. The reported coulombic efficiency of up to 97% with minor reduction in capacity opens a pathway to potentially address the polysulfide redox shuttle in Li–S batteries using tailored membranes. |
| Freie Schlagworte: | lithium–sulfur battery, polysulfide redox shuttle, etched ion track membrane, polyethylene terephthalate, PET, battery separator |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-204817 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 530 Physik 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Ionenstrahlmodifizierte Materialien |
| Hinterlegungsdatum: | 25 Mär 2024 10:24 |
| Letzte Änderung: | 26 Mär 2024 07:51 |
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| Suche nach Titel in: | TUfind oder in Google |
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- Etched ion-track membranes as tailored separators in Li–S batteries. (deposited 25 Mär 2024 10:24) [Gegenwärtig angezeigt]
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