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Effect of resting time on rheological properties of glass bead suspensions: Depletion and bridging force among particles

Ji, Yanliang ; Becker, Simon ; Lu, Zichen ; Mezhov, Alexander ; Klitzing, Regine von ; Wolfram, Schmidt ; Stephan, Dietmar (2024)
Effect of resting time on rheological properties of glass bead suspensions: Depletion and bridging force among particles.
In: Journal of the American Ceramic Society, 2023, 107 (1)
doi: 10.26083/tuprints-00026516
Artikel, Zweitveröffentlichung, Verlagsversion

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Kurzbeschreibung (Abstract)

The effect of resting time on the rheological properties of cement suspensions is generally explained by early formed structure and overconsumption of polycarboxylate superplasticizers (PCEs). In this paper, we propose that the influence of resting time on the rheological properties is closely related to size variation of non-absorbed PCE. To identify this, glass bead suspensions were prepared with various amounts of PCE and ionic solution, and their rheological properties were evaluated at various times. We found that the yield stress increases with time at higher PCE concentrations and higher ionic strength solutions. Adsorbed PCE during resting tends to bridge the particles rather than disperse them. In addition, it was found that hydrodynamic radius of PCE increased with resting time, and depletion forces resulting from non-absorbed PCE size changes correlate well with the increased yield stress.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Ji, Yanliang ; Becker, Simon ; Lu, Zichen ; Mezhov, Alexander ; Klitzing, Regine von ; Wolfram, Schmidt ; Stephan, Dietmar
Art des Eintrags: Zweitveröffentlichung
Titel: Effect of resting time on rheological properties of glass bead suspensions: Depletion and bridging force among particles
Sprache: Englisch
Publikationsjahr: 20 Februar 2024
Ort: Darmstadt
Publikationsdatum der Erstveröffentlichung: 6 November 2023
Ort der Erstveröffentlichung: Hoboken, NJ [u.a.]
Verlag: Wiley-Blackwell
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the American Ceramic Society
Jahrgang/Volume einer Zeitschrift: 107
(Heft-)Nummer: 1
Kollation: 16 Seiten
DOI: 10.26083/tuprints-00026516
URL / URN: https://tuprints.ulb.tu-darmstadt.de/26516
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Herkunft: Zweitveröffentlichungsservice
Kurzbeschreibung (Abstract):

The effect of resting time on the rheological properties of cement suspensions is generally explained by early formed structure and overconsumption of polycarboxylate superplasticizers (PCEs). In this paper, we propose that the influence of resting time on the rheological properties is closely related to size variation of non-absorbed PCE. To identify this, glass bead suspensions were prepared with various amounts of PCE and ionic solution, and their rheological properties were evaluated at various times. We found that the yield stress increases with time at higher PCE concentrations and higher ionic strength solutions. Adsorbed PCE during resting tends to bridge the particles rather than disperse them. In addition, it was found that hydrodynamic radius of PCE increased with resting time, and depletion forces resulting from non-absorbed PCE size changes correlate well with the increased yield stress.

Freie Schlagworte: depletion force, ionic strength, PCE, rheology, resting time
Status: Verlagsversion
URN: urn:nbn:de:tuda-tuprints-265162
Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 530 Physik
600 Technik, Medizin, angewandte Wissenschaften > 660 Technische Chemie
Fachbereich(e)/-gebiet(e): 05 Fachbereich Physik
05 Fachbereich Physik > Institut für Physik Kondensierter Materie (IPKM)
05 Fachbereich Physik > Institut für Physik Kondensierter Materie (IPKM) > Soft Matter at Interfaces (SMI)
Hinterlegungsdatum: 20 Feb 2024 08:16
Letzte Änderung: 05 Mär 2024 12:20
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