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Process Intensification for the Recovery of Hydrogen Cyanide in the Andrussow Process

Lehrich, Luca ; Adiche, Chafika (2024)
Process Intensification for the Recovery of Hydrogen Cyanide in the Andrussow Process.
In: Chemie Ingenieur Technik, 2023, 95 (10)
doi: 10.26083/tuprints-00024671
Artikel, Zweitveröffentlichung, Verlagsversion

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Kurzbeschreibung (Abstract)

The aim of this work was to determine a cost‐optimal design of the distillation unit of the Andrussow process. For this purpose, a feed with a mass flow rate of 121 t h⁻¹ and a concentration of ca. 2 wt % hydrogen cyanide (HCN) was considered. An approach for a cost‐optimal process intensification was developed with the goal to achieve the desired product qualities, while minimizing the organonitrile accumulation in the column. For this purpose, the simple distillation column of the established cost‐optimal design of the base case was extended to a configuration with a side stripper with taking into consideration heat integration in the process. It was found that this new configuration allows a much smaller accumulation of organonitriles in the main column; reducing thereby the operation issues of the process while decreasing considerably the total annual cost of the distillation unit by 61 % as compared to that of the base case design.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Lehrich, Luca ; Adiche, Chafika
Art des Eintrags: Zweitveröffentlichung
Titel: Process Intensification for the Recovery of Hydrogen Cyanide in the Andrussow Process
Sprache: Englisch
Publikationsjahr: 9 Februar 2024
Ort: Darmstadt
Publikationsdatum der Erstveröffentlichung: 2023
Ort der Erstveröffentlichung: Weinheim
Verlag: Wiley-VCH
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Chemie Ingenieur Technik
Jahrgang/Volume einer Zeitschrift: 95
(Heft-)Nummer: 10
DOI: 10.26083/tuprints-00024671
URL / URN: https://tuprints.ulb.tu-darmstadt.de/24671
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Herkunft: Zweitveröffentlichung DeepGreen
Kurzbeschreibung (Abstract):

The aim of this work was to determine a cost‐optimal design of the distillation unit of the Andrussow process. For this purpose, a feed with a mass flow rate of 121 t h⁻¹ and a concentration of ca. 2 wt % hydrogen cyanide (HCN) was considered. An approach for a cost‐optimal process intensification was developed with the goal to achieve the desired product qualities, while minimizing the organonitrile accumulation in the column. For this purpose, the simple distillation column of the established cost‐optimal design of the base case was extended to a configuration with a side stripper with taking into consideration heat integration in the process. It was found that this new configuration allows a much smaller accumulation of organonitriles in the main column; reducing thereby the operation issues of the process while decreasing considerably the total annual cost of the distillation unit by 61 % as compared to that of the base case design.

Freie Schlagworte: Andrussow process, Cost model, Distillation process, Heat integration, Organonitrile contaminants, Process intensification
Status: Verlagsversion
URN: urn:nbn:de:tuda-tuprints-246717
Sachgruppe der Dewey Dezimalklassifikatin (DDC): 600 Technik, Medizin, angewandte Wissenschaften > 620 Ingenieurwissenschaften und Maschinenbau
Fachbereich(e)/-gebiet(e): 16 Fachbereich Maschinenbau
16 Fachbereich Maschinenbau > Fachgebiet für Thermische Verfahrenstechnik (TVT)
Hinterlegungsdatum: 09 Feb 2024 14:04
Letzte Änderung: 12 Feb 2024 07:39
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