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Dynamic wetting properties of PDMS pseudo-brushes: Four-phase contact point dynamics case

Rostami, Peyman ; Hormozi, Mohammad Ali ; Soltwedel, Olaf ; Azizmalayeri, Reza ; von Klitzing, Regine ; Auernhammer, Günter K. (2024)
Dynamic wetting properties of PDMS pseudo-brushes: Four-phase contact point dynamics case.
In: The Journal of Chemical Physics, 2023, 158 (19)
doi: 10.26083/tuprints-00026515
Artikel, Zweitveröffentlichung, Verlagsversion

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Kurzbeschreibung (Abstract)

We investigate the wetting properties of PDMS (Polydimethylsiloxane) pseudo-brush anchored on glass substrates. These PDMS pseudobrushes exhibit a significantly lower contact angle hysteresis compared to hydrophobic silanized substrates. The effect of different molar masses of the used PDMS on the wetting properties seems negligible. The surface roughness and thickness of the PDMS pseudo-brush are measured by atomic force microscopy and x-ray reflectivity. The outcome shows that these surfaces are extremely smooth (topologically and chemically), which explains the reduction in contact angle hysteresis. These special features make this kind of surfaces very useful for wetting experiments. Here, the dynamics of the four-phase contact point are studied on these surfaces. The four-phase contact point dynamics on PDMS pseudo-brushes deviate substantially from its dynamics on other substrates. These changes depend only a little on the molar mass of the used PDMS. In general, PDMS pseudo-brushes increase the traveling speed of four-phase contact point on the surface and change the associated power law of position vs time.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Rostami, Peyman ; Hormozi, Mohammad Ali ; Soltwedel, Olaf ; Azizmalayeri, Reza ; von Klitzing, Regine ; Auernhammer, Günter K.
Art des Eintrags: Zweitveröffentlichung
Titel: Dynamic wetting properties of PDMS pseudo-brushes: Four-phase contact point dynamics case
Sprache: Englisch
Publikationsjahr: 5 Februar 2024
Ort: Darmstadt
Publikationsdatum der Erstveröffentlichung: 2023
Ort der Erstveröffentlichung: Melville, NY
Verlag: AIP Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: The Journal of Chemical Physics
Jahrgang/Volume einer Zeitschrift: 158
(Heft-)Nummer: 19
Kollation: 9 Seiten
DOI: 10.26083/tuprints-00026515
URL / URN: https://tuprints.ulb.tu-darmstadt.de/26515
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Herkunft: Zweitveröffentlichungsservice
Kurzbeschreibung (Abstract):

We investigate the wetting properties of PDMS (Polydimethylsiloxane) pseudo-brush anchored on glass substrates. These PDMS pseudobrushes exhibit a significantly lower contact angle hysteresis compared to hydrophobic silanized substrates. The effect of different molar masses of the used PDMS on the wetting properties seems negligible. The surface roughness and thickness of the PDMS pseudo-brush are measured by atomic force microscopy and x-ray reflectivity. The outcome shows that these surfaces are extremely smooth (topologically and chemically), which explains the reduction in contact angle hysteresis. These special features make this kind of surfaces very useful for wetting experiments. Here, the dynamics of the four-phase contact point are studied on these surfaces. The four-phase contact point dynamics on PDMS pseudo-brushes deviate substantially from its dynamics on other substrates. These changes depend only a little on the molar mass of the used PDMS. In general, PDMS pseudo-brushes increase the traveling speed of four-phase contact point on the surface and change the associated power law of position vs time.

ID-Nummer: Artikel-ID: 194703
Status: Verlagsversion
URN: urn:nbn:de:tuda-tuprints-265153
Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 530 Physik
500 Naturwissenschaften und Mathematik > 540 Chemie
Fachbereich(e)/-gebiet(e): 05 Fachbereich Physik
05 Fachbereich Physik > Institut für Physik Kondensierter Materie (IPKM)
05 Fachbereich Physik > Institut für Physik Kondensierter Materie (IPKM) > Soft Matter at Interfaces (SMI)
Hinterlegungsdatum: 05 Feb 2024 12:17
Letzte Änderung: 12 Mär 2024 09:20
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