Hempe, Matthias ; Paschek, Johanna ; Schelter, Jürgen ; Umbach, Anne ; Meerholz, Klaus ; Reggelin, Michael (2024)
Crosslinkable Bis(diphenylamine)‐Substituted Mixed Dihydroindeno[1,2‐b]fluorenes for Solution‐Processed Multilayer Organic Light‐Emitting Diodes.
In: ChemPlusChem, 2020, 85 (1)
doi: 10.26083/tuprints-00017468
Artikel, Zweitveröffentlichung, Verlagsversion

Kurzbeschreibung (Abstract)

The synthesis and application of a series of crosslinkable bis(diphenylamine)‐substituted mixed dihydroindeno[1,2‐b]fluorenes as model systems for the fabrication of solution‐processed, multilayer organic light‐emitting diodes (OLEDs) is described. Introducing a novel functionalization approach by C(sp³)−C(sp²) Suzuki‐Miyaura reactions, the synthesis is based on a modular strategy, leading to eight nearly isoelectronic derivatives that allow for the observation of structure‐property relationships in the context of crosslinkable hole‐transport materials, e. g., for use in OLEDs. By systematically altering structural parameters, such as the number of crosslinkable oxetane moieties per molecule (2–6 moieties) and their position of attachment (geminal and/or lateral), process‐relevant thermal properties such as thermal stability (Td95, 170‐350°C) and glass‐transition temperature (15‐100°C) can be influenced and allow for the investigation of their impact on the crosslinking behavior and the resulting device performance.

Typ des Eintrags:	Artikel
Erschienen:	2024
Autor(en):	Hempe, Matthias ; Paschek, Johanna ; Schelter, Jürgen ; Umbach, Anne ; Meerholz, Klaus ; Reggelin, Michael
Art des Eintrags:	Zweitveröffentlichung
Titel:	Crosslinkable Bis(diphenylamine)‐Substituted Mixed Dihydroindeno[1,2‐b]fluorenes for Solution‐Processed Multilayer Organic Light‐Emitting Diodes
Sprache:	Englisch
Publikationsjahr:	30 Januar 2024
Ort:	Darmstadt
Publikationsdatum der Erstveröffentlichung:	2020
Ort der Erstveröffentlichung:	Weinheim
Verlag:	Wiley-VCH
Titel der Zeitschrift, Zeitung oder Schriftenreihe:	ChemPlusChem
Jahrgang/Volume einer Zeitschrift:	85
(Heft-)Nummer:	1
DOI:	10.26083/tuprints-00017468
URL / URN:	https://tuprints.ulb.tu-darmstadt.de/17468
Zugehörige Links:	Verlags-DOI
Herkunft:	Zweitveröffentlichung DeepGreen
Kurzbeschreibung (Abstract):	The synthesis and application of a series of crosslinkable bis(diphenylamine)‐substituted mixed dihydroindeno[1,2‐b]fluorenes as model systems for the fabrication of solution‐processed, multilayer organic light‐emitting diodes (OLEDs) is described. Introducing a novel functionalization approach by C(sp³)−C(sp²) Suzuki‐Miyaura reactions, the synthesis is based on a modular strategy, leading to eight nearly isoelectronic derivatives that allow for the observation of structure‐property relationships in the context of crosslinkable hole‐transport materials, e. g., for use in OLEDs. By systematically altering structural parameters, such as the number of crosslinkable oxetane moieties per molecule (2–6 moieties) and their position of attachment (geminal and/or lateral), process‐relevant thermal properties such as thermal stability (Td95, 170‐350°C) and glass‐transition temperature (15‐100°C) can be influenced and allow for the investigation of their impact on the crosslinking behavior and the resulting device performance.
Alternatives oder übersetztes Abstract:	Alternatives Abstract Sprache Crosslinkable OLED materials: A series of eight crosslinkable, arylamine-substituted dihydroindeno[1,2-b]fluorenes was synthesized by using a novel approach for attaching alkyl-bound oxetane moieties. The set of molecules allows for the observation of structure–property relationships in the context of crosslinkable hole-transport materials, which were evaluated by thermal analysis, crosslinking behavior, and the resulting device performance. Englisch
Freie Schlagworte:	crosslinking, materials science, OLEDs, oxetanes, polymerization
Status:	Verlagsversion
URN:	urn:nbn:de:tuda-tuprints-174685
Sachgruppe der Dewey Dezimalklassifikatin (DDC):	500 Naturwissenschaften und Mathematik > 540 Chemie
Fachbereich(e)/-gebiet(e):	07 Fachbereich Chemie 07 Fachbereich Chemie > Clemens-Schöpf-Institut 07 Fachbereich Chemie > Clemens-Schöpf-Institut > Fachgebiet Organische Chemie
Hinterlegungsdatum:	30 Jan 2024 13:40
Letzte Änderung:	31 Jan 2024 07:45
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Zugehörige Links:	Verlags-DOI
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Verfügbare Versionen dieses Eintrags

• Crosslinkable Bis(diphenylamine)‐Substituted Mixed Dihydroindeno[1,2‐b]fluorenes for Solution‐Processed Multilayer Organic Light‐Emitting Diodes. (deposited 30 Jan 2024 13:40) [Gegenwärtig angezeigt]
  • Crosslinkable bis(diphenylamine)‐substituted mixed dihydroindeno[1,2‐b]fluorenes for solution‐processed multilayer organic light‐emitting diodes. (deposited 31 Jan 2024 07:46)

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