Bies, Thorsten ; Hoffmann, Rudolf C. ; Stöter, Matthias ; Huber, Adalbert ; Schneider, Jörg J. (2024)
Environmentally Benign Solution‐Based Procedure for the Fabrication of Metal Oxide Coatings on Metallic Pigments.
In: ChemistryOpen, 2020, 9 (12)
doi: 10.26083/tuprints-00017789
Artikel, Zweitveröffentlichung, Verlagsversion
 | Es ist eine neuere Version dieses Eintrags verfügbar. |
Kurzbeschreibung (Abstract)
Aluminum pigments were coated with Fe₂O₃ and CuO by solution‐based thermal decomposition of the urea nitrate compounds hexakisureairon(III)nitrate and tetrakisureacopper(II)nitrate. The deposition process was optimized to obtain homogeneously coated aluminum pigments. The growth of the surface coatings was controlled by investigation with scanning electron microscopy, energy dispersive X‐ray spectroscopy and static light scattering as well as infrared, X‐ray diffraction and thermogravimetric analysis. The iron precursor showed an incomplete decomposition in solution, incorporating traces of urea molecules inside the coatings while the copper precursor showed complete dissociation accompanied by in situ formation of amine complexes. The amount of organic residues resulting from ligand fragments in the final oxide coatings could be reduced to 22 % for the iron oxide and 12 % for the copper oxide by further temperature treatment in solution (259 °C). Colorimetric investigations of the obtained pigments revealed an excellent hiding power, outperforming the pigments used in current state‐of‐the‐art formulations.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Bies, Thorsten ; Hoffmann, Rudolf C. ; Stöter, Matthias ; Huber, Adalbert ; Schneider, Jörg J. |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Environmentally Benign Solution‐Based Procedure for the Fabrication of Metal Oxide Coatings on Metallic Pigments |
| Sprache: | Englisch |
| Publikationsjahr: | 30 Januar 2024 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2020 |
| Ort der Erstveröffentlichung: | Weinheim |
| Verlag: | Wiley-VCH |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | ChemistryOpen |
| Jahrgang/Volume einer Zeitschrift: | 9 |
| (Heft-)Nummer: | 12 |
| DOI: | 10.26083/tuprints-00017789 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/17789 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Aluminum pigments were coated with Fe₂O₃ and CuO by solution‐based thermal decomposition of the urea nitrate compounds hexakisureairon(III)nitrate and tetrakisureacopper(II)nitrate. The deposition process was optimized to obtain homogeneously coated aluminum pigments. The growth of the surface coatings was controlled by investigation with scanning electron microscopy, energy dispersive X‐ray spectroscopy and static light scattering as well as infrared, X‐ray diffraction and thermogravimetric analysis. The iron precursor showed an incomplete decomposition in solution, incorporating traces of urea molecules inside the coatings while the copper precursor showed complete dissociation accompanied by in situ formation of amine complexes. The amount of organic residues resulting from ligand fragments in the final oxide coatings could be reduced to 22 % for the iron oxide and 12 % for the copper oxide by further temperature treatment in solution (259 °C). Colorimetric investigations of the obtained pigments revealed an excellent hiding power, outperforming the pigments used in current state‐of‐the‐art formulations. |
| Freie Schlagworte: | copper, iron, metal oxide thin films, special effect pigments, urea-nitrate compounds |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-177893 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Anorganische Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut |
| Hinterlegungsdatum: | 30 Jan 2024 13:58 |
| Letzte Änderung: | 31 Jan 2024 07:27 |
| PPN: | |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
- Environmentally Benign Solution‐Based Procedure for the Fabrication of Metal Oxide Coatings on Metallic Pigments. (deposited 30 Jan 2024 13:58) [Gegenwärtig angezeigt]
 |
Frage zum Eintrag |
Optionen (nur für Redakteure)
 |
Redaktionelle Details anzeigen |
Drucken
Impressum