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High-performance LaFe11.6Si1.4Hy/Al composites for magnetic refrigeration: a good combination of magnetocaloric effect, mechanical properties, and thermal conductivity

Zhang, Mingxiao ; Shao, Yanyan ; Li, Chunhui ; Zhang, Yifei ; Sun, Wen ; Wei, Zhiyang ; Skokov, Konstantin P. ; Liu, Jian ; Yan, Aru (2023)
High-performance LaFe11.6Si1.4Hy/Al composites for magnetic refrigeration: a good combination of magnetocaloric effect, mechanical properties, and thermal conductivity.
In: Journal of Alloys and Compounds, 962
doi: 10.1016/j.jallcom.2023.171123
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Bulk LaFe11.6Si1.4Hy/Al composites with the saturated hydrogen content were prepared by hot pressing and subsequent hydrogenation. Al particles were dramatically deformed when pressed at 773 K, and a reaction of La(Fe,Si)13 and Al phases took place at 873 K. The reinforced skeleton structure consisting of malleable Al phases in the composites allows brittle La(Fe,Si)13Hy particles to be well bonded after hydrogen absorption. As a result, these LaFe11.6Si1.4Hy/Al hydrides show a good comprehensive performance for magnetic refrigeration, i.e., large entropy changes of 9.8–12.5 J/kg K under 2 T, large adiabatic temperature changes of 3.36–3.97 K under 1.9 T, high thermal conductivity of 11.4–45.6 W/m K, and high bending strength of 16.8–48.2 MPa. Particularly, the 20 wt% Al composite possesses a compressive strength of 122 MPa and plastic deformation of 4.6 %.

Typ des Eintrags: Artikel
Erschienen: 2023
Autor(en): Zhang, Mingxiao ; Shao, Yanyan ; Li, Chunhui ; Zhang, Yifei ; Sun, Wen ; Wei, Zhiyang ; Skokov, Konstantin P. ; Liu, Jian ; Yan, Aru
Art des Eintrags: Bibliographie
Titel: High-performance LaFe11.6Si1.4Hy/Al composites for magnetic refrigeration: a good combination of magnetocaloric effect, mechanical properties, and thermal conductivity
Sprache: Englisch
Publikationsjahr: 5 November 2023
Verlag: Elsevier
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Alloys and Compounds
Jahrgang/Volume einer Zeitschrift: 962
DOI: 10.1016/j.jallcom.2023.171123
Kurzbeschreibung (Abstract):

Bulk LaFe11.6Si1.4Hy/Al composites with the saturated hydrogen content were prepared by hot pressing and subsequent hydrogenation. Al particles were dramatically deformed when pressed at 773 K, and a reaction of La(Fe,Si)13 and Al phases took place at 873 K. The reinforced skeleton structure consisting of malleable Al phases in the composites allows brittle La(Fe,Si)13Hy particles to be well bonded after hydrogen absorption. As a result, these LaFe11.6Si1.4Hy/Al hydrides show a good comprehensive performance for magnetic refrigeration, i.e., large entropy changes of 9.8–12.5 J/kg K under 2 T, large adiabatic temperature changes of 3.36–3.97 K under 1.9 T, high thermal conductivity of 11.4–45.6 W/m K, and high bending strength of 16.8–48.2 MPa. Particularly, the 20 wt% Al composite possesses a compressive strength of 122 MPa and plastic deformation of 4.6 %.

Freie Schlagworte: metal-bonded composites, hot pressing, magnetocaloric effect, thermal conductivity, mechanical properties
Zusätzliche Informationen:

Artikel-ID: 171123

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Funktionale Materialien
Hinterlegungsdatum: 22 Jan 2024 06:43
Letzte Änderung: 22 Jan 2024 07:46
PPN: 514874015
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