Zhang, Shan-Ting ; Vitrant, Guy ; Pernot, Etienne ; Jiménez, Carmen ; Muñoz-Rojas, David ; Bellet, Daniel (2018)
Hazy Al₂O₃-FTO nanocomposites: a comparative study with FTO-based nanocomposites integrating ZnO and S:TiO₂ nanostructures.
In: Nanomaterials, 8 (6)
doi: 10.3390/nano8060440
Artikel, Bibliographie
Dies ist die neueste Version dieses Eintrags.
Kurzbeschreibung (Abstract)
In this study, we report the use of Al₂O₃ nanoparticles in combination with fluorine doped tin oxide (F:SnO₂, aka FTO) thin films to form hazy Al₂O₃-FTO nanocomposites. In comparison to previously reported FTO-based nanocomposites integrating ZnO and sulfur doped TiO₂ (S:TiO₂) nanoparticles (i.e., ZnO-FTO and S:TiO₂-FTO nanocomposites), the newly developed Al₂O₃-FTO nanocomposites show medium haze factor HT of about 30%, while they exhibit the least loss in total transmittance Ttot. In addition, Al₂O₃-FTO nanocomposites present a low fraction of large-sized nanoparticle agglomerates with equivalent radius req > 1 μm; effectively 90% of the nanoparticle agglomerates show req < 750 nm. The smaller feature size in Al₂O₃-FTO nanocomposites, as compared to ZnO-FTO and S:TiO₂-FTO nanocomposites, makes them more suitable for applications that are sensitive to roughness and large-sized features. With the help of a simple optical model developed in this work, we have simulated the optical scattering by a single nanoparticle agglomerate characterized by bottom radius r₀, top radius r₁, and height h. It is found that r₀ is the main factor affecting the HT(λ), which indicates that the haze factor of Al₂O₃-FTO and related FTO nanocomposites is mainly determined by the total surface coverage of all the nanoparticle agglomerates present.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2018 |
| Autor(en): | Zhang, Shan-Ting ; Vitrant, Guy ; Pernot, Etienne ; Jiménez, Carmen ; Muñoz-Rojas, David ; Bellet, Daniel |
| Art des Eintrags: | Bibliographie |
| Titel: | Hazy Al₂O₃-FTO nanocomposites: a comparative study with FTO-based nanocomposites integrating ZnO and S:TiO₂ nanostructures |
| Sprache: | Englisch |
| Publikationsjahr: | 2018 |
| Ort: | Basel |
| Verlag: | MDPI |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Nanomaterials |
| Jahrgang/Volume einer Zeitschrift: | 8 |
| (Heft-)Nummer: | 6 |
| Kollation: | 14 Seiten |
| DOI: | 10.3390/nano8060440 |
| Zugehörige Links: | |
| Kurzbeschreibung (Abstract): | In this study, we report the use of Al₂O₃ nanoparticles in combination with fluorine doped tin oxide (F:SnO₂, aka FTO) thin films to form hazy Al₂O₃-FTO nanocomposites. In comparison to previously reported FTO-based nanocomposites integrating ZnO and sulfur doped TiO₂ (S:TiO₂) nanoparticles (i.e., ZnO-FTO and S:TiO₂-FTO nanocomposites), the newly developed Al₂O₃-FTO nanocomposites show medium haze factor HT of about 30%, while they exhibit the least loss in total transmittance Ttot. In addition, Al₂O₃-FTO nanocomposites present a low fraction of large-sized nanoparticle agglomerates with equivalent radius req > 1 μm; effectively 90% of the nanoparticle agglomerates show req < 750 nm. The smaller feature size in Al₂O₃-FTO nanocomposites, as compared to ZnO-FTO and S:TiO₂-FTO nanocomposites, makes them more suitable for applications that are sensitive to roughness and large-sized features. With the help of a simple optical model developed in this work, we have simulated the optical scattering by a single nanoparticle agglomerate characterized by bottom radius r₀, top radius r₁, and height h. It is found that r₀ is the main factor affecting the HT(λ), which indicates that the haze factor of Al₂O₃-FTO and related FTO nanocomposites is mainly determined by the total surface coverage of all the nanoparticle agglomerates present. |
| Freie Schlagworte: | FTO, nanocomposite, Al₂O₃, haze factor, optical scattering, TCO |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 540 Chemie 600 Technik, Medizin, angewandte Wissenschaften > 660 Technische Chemie |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Elektronenstruktur von Materialien |
| Hinterlegungsdatum: | 17 Jan 2024 08:55 |
| Letzte Änderung: | 17 Jan 2024 08:55 |
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Verfügbare Versionen dieses Eintrags
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Hazy Al₂O₃-FTO Nanocomposites: A Comparative Study with FTO-Based Nanocomposites Integrating ZnO and S:TiO₂ Nanostructures. (deposited 16 Jan 2024 10:19)
- Hazy Al₂O₃-FTO nanocomposites: a comparative study with FTO-based nanocomposites integrating ZnO and S:TiO₂ nanostructures. (deposited 17 Jan 2024 08:55) [Gegenwärtig angezeigt]
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