Keshavarzi, Behnam ; Mahmoudvand, Mohsen ; Javadi, Aliyar ; Bahramian, Alireza ; Miller, Reinhard ; Eckert, Kerstin (2024)
Salt Effects on Formation and Stability of Colloidal Gas Aphrons Produced by Anionic and Zwitterionic Surfactants in Xanthan Gum Solution.
In: Colloids and Interfaces, 2020, 4 (1)
doi: 10.26083/tuprints-00016109
Artikel, Zweitveröffentlichung, Verlagsversion
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Kurzbeschreibung (Abstract)
This work is devoted to the influence of NaCl salt concentration on the formation and stability of colloidal gas aphrons (CGA) produced by the anionic surfactant sodium dodecyl sulfate (SDS) and zwitterionic surfactant coco amido propyl betaine (CAPB) in the presence of xanthan gum (XG) as a stabilizer. Dynamic surface tension measurements as well as volume and half-life time of the produced foams are considered for stability analysis. A sharp decrease of the half-life time and volume of the CGAs at NaCl concentrations larger than 20,000 ppm was observed, which was attributed to the precipitation of SDS in the solution. The mentioned SDS precipitation altered the dynamic surface tension behavior, dilational surface elasticity, and turbidity of the solution. The main reason for the precipitation of SDS is the increased Krafft point caused by the addition of salt. However, for the zwitterionic surfactant CAPB, the effects of added NaCl on the interfacial properties required for CGAs production was negligible due to the simultaneous effects on the cationic and anionic head groups in the CAPB leading to negligible changes in the net repulsion forces. Yet, an overall reduction in the half-life time of CGAs with increasing salt concentration, even when we have no precipitation, was observed for both surfactants, which could be explained by the reduction in the ability of XG to increase the viscosity with increasing salt concentration.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Keshavarzi, Behnam ; Mahmoudvand, Mohsen ; Javadi, Aliyar ; Bahramian, Alireza ; Miller, Reinhard ; Eckert, Kerstin |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Salt Effects on Formation and Stability of Colloidal Gas Aphrons Produced by Anionic and Zwitterionic Surfactants in Xanthan Gum Solution |
| Sprache: | Englisch |
| Publikationsjahr: | 16 Januar 2024 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2020 |
| Ort der Erstveröffentlichung: | Basel |
| Verlag: | MDPI |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Colloids and Interfaces |
| Jahrgang/Volume einer Zeitschrift: | 4 |
| (Heft-)Nummer: | 1 |
| Kollation: | 9 Seiten |
| DOI: | 10.26083/tuprints-00016109 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/16109 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | This work is devoted to the influence of NaCl salt concentration on the formation and stability of colloidal gas aphrons (CGA) produced by the anionic surfactant sodium dodecyl sulfate (SDS) and zwitterionic surfactant coco amido propyl betaine (CAPB) in the presence of xanthan gum (XG) as a stabilizer. Dynamic surface tension measurements as well as volume and half-life time of the produced foams are considered for stability analysis. A sharp decrease of the half-life time and volume of the CGAs at NaCl concentrations larger than 20,000 ppm was observed, which was attributed to the precipitation of SDS in the solution. The mentioned SDS precipitation altered the dynamic surface tension behavior, dilational surface elasticity, and turbidity of the solution. The main reason for the precipitation of SDS is the increased Krafft point caused by the addition of salt. However, for the zwitterionic surfactant CAPB, the effects of added NaCl on the interfacial properties required for CGAs production was negligible due to the simultaneous effects on the cationic and anionic head groups in the CAPB leading to negligible changes in the net repulsion forces. Yet, an overall reduction in the half-life time of CGAs with increasing salt concentration, even when we have no precipitation, was observed for both surfactants, which could be explained by the reduction in the ability of XG to increase the viscosity with increasing salt concentration. |
| Freie Schlagworte: | Colloidal gas aphrons, foam formation and stability, drilling fluid, dynamic surface tension, interfacial rheology, cocoamidopropyl betaine, sodium dodecyl sulfate, NaCl |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-161091 |
| Zusätzliche Informationen: | This article belongs to the Special Issue Ion Specific Effects in Colloid and Surface Science – Where Biology, Chemistry and Physics Meet |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 530 Physik 500 Naturwissenschaften und Mathematik > 540 Chemie 600 Technik, Medizin, angewandte Wissenschaften > 620 Ingenieurwissenschaften und Maschinenbau |
| Fachbereich(e)/-gebiet(e): | 05 Fachbereich Physik 05 Fachbereich Physik > Institut für Physik Kondensierter Materie (IPKM) |
| Hinterlegungsdatum: | 16 Jan 2024 12:22 |
| Letzte Änderung: | 18 Jan 2024 12:08 |
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| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
- Salt Effects on Formation and Stability of Colloidal Gas Aphrons Produced by Anionic and Zwitterionic Surfactants in Xanthan Gum Solution. (deposited 16 Jan 2024 12:22) [Gegenwärtig angezeigt]
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