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Interfacial Properties of Tridecyl Dimethyl Phosphine Oxide Adsorbed at the Surface of a Solution Drop in Hexane Saturated Air

Fainerman, Valentin B. ; Aksenenko, Eugene V. ; Makievski, Alexander V. ; Liggieri, Libero ; Mucic, Nenad ; Javadi, Aliyar ; Kovalchuk, Volodymyr I. ; Miller, Reinhard (2024)
Interfacial Properties of Tridecyl Dimethyl Phosphine Oxide Adsorbed at the Surface of a Solution Drop in Hexane Saturated Air.
In: Colloids and Interfaces, 2020, 4 (2)
doi: 10.26083/tuprints-00016610
Artikel, Zweitveröffentlichung, Verlagsversion

Kurzbeschreibung (Abstract)

The surface tension of C₁₃DMPO aqueous solution drops in hexane vapor is studied using the drop profile method. The hexane was injected into the measuring cell at three different conditions: before the formation of the solution drop, at a certain moment during the adsorption process, and after reaching the equilibrium of surfactant adsorption. The surface tension values for all experiments at the same concentration and different injection situations ultimately coincide with each other after attaining the final equilibration stage. The equilibrium surface tension isotherms of C₁₃DMPO solutions, and the adsorption of both components—surfactant and hexane—were calculated. It was shown that the presence of surfactant leads to an increased hexane adsorption.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Fainerman, Valentin B. ; Aksenenko, Eugene V. ; Makievski, Alexander V. ; Liggieri, Libero ; Mucic, Nenad ; Javadi, Aliyar ; Kovalchuk, Volodymyr I. ; Miller, Reinhard
Art des Eintrags: Zweitveröffentlichung
Titel: Interfacial Properties of Tridecyl Dimethyl Phosphine Oxide Adsorbed at the Surface of a Solution Drop in Hexane Saturated Air
Sprache: Englisch
Publikationsjahr: 16 Januar 2024
Ort: Darmstadt
Publikationsdatum der Erstveröffentlichung: 2020
Ort der Erstveröffentlichung: Basel
Verlag: MDPI
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Colloids and Interfaces
Jahrgang/Volume einer Zeitschrift: 4
(Heft-)Nummer: 2
Kollation: 14 Seiten
DOI: 10.26083/tuprints-00016610
URL / URN: https://tuprints.ulb.tu-darmstadt.de/16610
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Herkunft: Zweitveröffentlichung DeepGreen
Kurzbeschreibung (Abstract):

The surface tension of C₁₃DMPO aqueous solution drops in hexane vapor is studied using the drop profile method. The hexane was injected into the measuring cell at three different conditions: before the formation of the solution drop, at a certain moment during the adsorption process, and after reaching the equilibrium of surfactant adsorption. The surface tension values for all experiments at the same concentration and different injection situations ultimately coincide with each other after attaining the final equilibration stage. The equilibrium surface tension isotherms of C₁₃DMPO solutions, and the adsorption of both components—surfactant and hexane—were calculated. It was shown that the presence of surfactant leads to an increased hexane adsorption.

Freie Schlagworte: drop profile analysis tensiometry, surfactant adsorption, solution-alkane vapor interface, dynamic surface tension, thermodynamic model, non-ionic surfactant
Status: Verlagsversion
URN: urn:nbn:de:tuda-tuprints-166109
Zusätzliche Informationen:

This article belongs to the Special Issue Exclusive Papers of the Editorial Board Members of Colloids and Interfaces

Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 530 Physik
500 Naturwissenschaften und Mathematik > 540 Chemie
Fachbereich(e)/-gebiet(e): 05 Fachbereich Physik
05 Fachbereich Physik > Institut für Physik Kondensierter Materie (IPKM)
Hinterlegungsdatum: 16 Jan 2024 10:33
Letzte Änderung: 18 Jan 2024 12:11
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