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H₂O collisional broadening coefficients at 1.37 µm and their temperature dependence: a metrology approach

Nwaboh, Javis A. ; Werhahn, Olav ; Ebert, Volker (2021)
H₂O collisional broadening coefficients at 1.37 µm and their temperature dependence: a metrology approach.
In: Applied Sciences, 11 (12)
doi: 10.3390/app11125341
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

We report self- and air collisional broadening coefficients for the H₂O line at 7299.43 cm⁻¹ and corresponding temperature coefficients for a temperature range spanning 293–573 K. New laser spectroscopic setups specifically designed for this purpose have been developed and are described. The line parameters reported here are in good agreement with those values reported in the HITRAN 2020 database, but the uncertainties have been reduced by factors of about 4, 1.3 and 4.4 for the self-broadening coefficient, air broadening coefficient and the temperature exponent of air broadening, respectively. Further, we combined our measurement approach with metrological data quality objectives, addressing the traceability of the results to the international system of units (SI) and evaluated the uncertainties following the guide to the expression of uncertainty in measurement (GUM).

Typ des Eintrags: Artikel
Erschienen: 2021
Autor(en): Nwaboh, Javis A. ; Werhahn, Olav ; Ebert, Volker
Art des Eintrags: Bibliographie
Titel: H₂O collisional broadening coefficients at 1.37 µm and their temperature dependence: a metrology approach
Sprache: Englisch
Publikationsjahr: 2021
Ort: Basel
Verlag: MDPI
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Applied Sciences
Jahrgang/Volume einer Zeitschrift: 11
(Heft-)Nummer: 12
Kollation: 12 Seiten
DOI: 10.3390/app11125341
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Kurzbeschreibung (Abstract):

We report self- and air collisional broadening coefficients for the H₂O line at 7299.43 cm⁻¹ and corresponding temperature coefficients for a temperature range spanning 293–573 K. New laser spectroscopic setups specifically designed for this purpose have been developed and are described. The line parameters reported here are in good agreement with those values reported in the HITRAN 2020 database, but the uncertainties have been reduced by factors of about 4, 1.3 and 4.4 for the self-broadening coefficient, air broadening coefficient and the temperature exponent of air broadening, respectively. Further, we combined our measurement approach with metrological data quality objectives, addressing the traceability of the results to the international system of units (SI) and evaluated the uncertainties following the guide to the expression of uncertainty in measurement (GUM).

Freie Schlagworte: laser spectroscopy, gas metrology, water vapor, collisional broadening, broadening temperature dependence
Zusätzliche Informationen:

This article belongs to the Special Issue Diode Laser Spectroscopy – Robust Sensing for Environmental and Industrial Applications

Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 530 Physik
600 Technik, Medizin, angewandte Wissenschaften > 620 Ingenieurwissenschaften und Maschinenbau
Fachbereich(e)/-gebiet(e): 16 Fachbereich Maschinenbau
16 Fachbereich Maschinenbau > Fachgebiet Reaktive Strömungen und Messtechnik (RSM)
Hinterlegungsdatum: 15 Jan 2024 07:50
Letzte Änderung: 16 Jan 2024 09:48
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