Laskowska, Magdalena ; Nowak, Anna ; Dulski, Mateusz ; Weigl, Peter ; Blochowicz, Thomas ; Laskowski, Łukasz (2024)
Spherical Silica Functionalized by 2-Naphthalene Methanol Luminophores as a Phosphorescence Sensor.
In: International Journal of Molecular Sciences, 2021, 22 (24)
doi: 10.26083/tuprints-00022183
Artikel, Zweitveröffentlichung, Verlagsversion
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Kurzbeschreibung (Abstract)
Photoluminescence is known to have huge potential for applications in studying biological systems. In that respect, phosphorescent dye molecules open the possibility to study the local slow solvent dynamics close to hard and soft surfaces and interfaces using the triplet state (TSD: triplet state solvation dynamics). However, for that purpose, probe molecules with efficient phosphorescence features are required with a fixed location on the surface. In this article, a potential TSD probe is presented in the form of a nanocomposite: we synthesize spherical silica particles with 2-naphthalene methanol molecules attached to the surface with a predefined surface density. The synthesis procedure is described in detail, and the obtained materials are characterized employing transmission electron microscopy imaging, Raman, and X-ray photoelectron spectroscopy. Finally, TSD experiments are carried out in order to confirm the phosphorescence properties of the obtained materials and the route to develop phosphorescent sensors at silica surfaces based on the presented results is discussed.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Laskowska, Magdalena ; Nowak, Anna ; Dulski, Mateusz ; Weigl, Peter ; Blochowicz, Thomas ; Laskowski, Łukasz |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Spherical Silica Functionalized by 2-Naphthalene Methanol Luminophores as a Phosphorescence Sensor |
| Sprache: | Englisch |
| Publikationsjahr: | 12 Januar 2024 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2021 |
| Ort der Erstveröffentlichung: | Basel |
| Verlag: | MDPI |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | International Journal of Molecular Sciences |
| Jahrgang/Volume einer Zeitschrift: | 22 |
| (Heft-)Nummer: | 24 |
| Kollation: | 15 Seiten |
| DOI: | 10.26083/tuprints-00022183 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/22183 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Photoluminescence is known to have huge potential for applications in studying biological systems. In that respect, phosphorescent dye molecules open the possibility to study the local slow solvent dynamics close to hard and soft surfaces and interfaces using the triplet state (TSD: triplet state solvation dynamics). However, for that purpose, probe molecules with efficient phosphorescence features are required with a fixed location on the surface. In this article, a potential TSD probe is presented in the form of a nanocomposite: we synthesize spherical silica particles with 2-naphthalene methanol molecules attached to the surface with a predefined surface density. The synthesis procedure is described in detail, and the obtained materials are characterized employing transmission electron microscopy imaging, Raman, and X-ray photoelectron spectroscopy. Finally, TSD experiments are carried out in order to confirm the phosphorescence properties of the obtained materials and the route to develop phosphorescent sensors at silica surfaces based on the presented results is discussed. |
| Freie Schlagworte: | 2-naphthalenemethanol, phosphorescence, triplet state solvation dynamics, nanocomposite |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-221837 |
| Zusätzliche Informationen: | This article belongs to the Special Issue Interactions of Nanoparticles with Biomolecules |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 530 Physik |
| Fachbereich(e)/-gebiet(e): | 05 Fachbereich Physik 05 Fachbereich Physik > Institut für Angewandte Physik 05 Fachbereich Physik > Institut für Physik Kondensierter Materie (IPKM) |
| Hinterlegungsdatum: | 12 Jan 2024 14:02 |
| Letzte Änderung: | 05 Mär 2024 11:18 |
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| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
- Spherical Silica Functionalized by 2-Naphthalene Methanol Luminophores as a Phosphorescence Sensor. (deposited 12 Jan 2024 14:02) [Gegenwärtig angezeigt]
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