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Enhancement of heavy ion track-etching in polyimide membranes with organic solvents

Froehlich, Kristina ; Scheuerlein, Martin Christoph ; Ali, Mubarak ; Nasir, Saima ; Ensinger, Wolfgang (2024)
Enhancement of heavy ion track-etching in polyimide membranes with organic solvents.
In: Nanotechnology, 2021, 33 (4)
doi: 10.26083/tuprints-00020485
Artikel, Zweitveröffentlichung, Verlagsversion

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Kurzbeschreibung (Abstract)

The effect of organic solvents on the ion track-etching of polyimide (PI) membranes is studied to enhance the nanopore fabrication process and the control over pore diameter growth. To this end, two approaches are employed to investigate the influence of organic solvents on the nanopore fabrication in PI membranes. In the first approach, the heavy ion irradiated PI samples are pretreated with organic solvents and then chemically etched with sodium hypochlorite (NaOCl) solution, resulting up to ∼4.4 times larger pore size compared to untreated ones. The second approach is based on a single-step track-etching process where the etchant (NaOCl) solution contains varying amounts of organic solvent (by vol%). The experimental data shows that a significant increase in both the bulk-etch and track-etch rates is observed by using the etchant mixture, which leads to ∼47% decrease in the nanopore fabrication time. This enhancement of nanopore fabrication process in PI membranes would open up new opportunities for their implementation in various potential applications.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Froehlich, Kristina ; Scheuerlein, Martin Christoph ; Ali, Mubarak ; Nasir, Saima ; Ensinger, Wolfgang
Art des Eintrags: Zweitveröffentlichung
Titel: Enhancement of heavy ion track-etching in polyimide membranes with organic solvents
Sprache: Englisch
Publikationsjahr: 9 Januar 2024
Ort: Darmstadt
Publikationsdatum der Erstveröffentlichung: 2021
Ort der Erstveröffentlichung: Bristol
Verlag: IOP Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Nanotechnology
Jahrgang/Volume einer Zeitschrift: 33
(Heft-)Nummer: 4
Kollation: 12 Seiten
DOI: 10.26083/tuprints-00020485
URL / URN: https://tuprints.ulb.tu-darmstadt.de/20485
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Herkunft: Zweitveröffentlichung DeepGreen
Kurzbeschreibung (Abstract):

The effect of organic solvents on the ion track-etching of polyimide (PI) membranes is studied to enhance the nanopore fabrication process and the control over pore diameter growth. To this end, two approaches are employed to investigate the influence of organic solvents on the nanopore fabrication in PI membranes. In the first approach, the heavy ion irradiated PI samples are pretreated with organic solvents and then chemically etched with sodium hypochlorite (NaOCl) solution, resulting up to ∼4.4 times larger pore size compared to untreated ones. The second approach is based on a single-step track-etching process where the etchant (NaOCl) solution contains varying amounts of organic solvent (by vol%). The experimental data shows that a significant increase in both the bulk-etch and track-etch rates is observed by using the etchant mixture, which leads to ∼47% decrease in the nanopore fabrication time. This enhancement of nanopore fabrication process in PI membranes would open up new opportunities for their implementation in various potential applications.

Freie Schlagworte: heavy ion irradiation, track-etching, organic solvents, nanopores, polyimide
Status: Verlagsversion
URN: urn:nbn:de:tuda-tuprints-204855
Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 530 Physik
500 Naturwissenschaften und Mathematik > 540 Chemie
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialanalytik
Hinterlegungsdatum: 09 Jan 2024 10:17
Letzte Änderung: 10 Jan 2024 08:07
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