Hock, Sebastian ; Lucas, Martin ; Kolle‐Görgen, Eva ; Mellin, Maximilian ; Hofmann, Jan P. ; Rose, Marcus (2023)
[Pd(2‐pymo)₂]n/Al₂O₃ as MOF Single Site Catalyst for the Selective Hydrogenation of Acetylene.
In: ChemCatChem, 2023, 15 (9)
doi: 10.26083/tuprints-00024530
Artikel, Zweitveröffentlichung, Verlagsversion
 | Es ist eine neuere Version dieses Eintrags verfügbar. |
Kurzbeschreibung (Abstract)
Despite the great potential of metal-organic frameworks (MOFs) in catalysis, industrial applications are still scarce. This is mainly due to a lack of performance when changing from idealized lab conditions towards realistic conditions of the actual application. In this work, we demonstrate the applicability and outstanding catalytic performance of an alumina-supported [Pd(2-pymo)₂]n MOF catalyst in the selective hydrogenation of acetylene to ethylene under industrial front-end conditions. It shows a competitive performance to an industrial benchmark catalyst and even exceeds it in terms of ethane selectivity due to the combination of well-defined isolated Pd active sites and synergies due to MOF-support-interactions. The high stability was proven for up to 60 h time-on-stream and supported by XPS and XRD structural analysis.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2023 |
| Autor(en): | Hock, Sebastian ; Lucas, Martin ; Kolle‐Görgen, Eva ; Mellin, Maximilian ; Hofmann, Jan P. ; Rose, Marcus |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | [Pd(2‐pymo)₂]n/Al₂O₃ as MOF Single Site Catalyst for the Selective Hydrogenation of Acetylene |
| Sprache: | Englisch |
| Publikationsjahr: | 20 November 2023 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 5 Mai 2023 |
| Ort der Erstveröffentlichung: | Weinheim |
| Verlag: | Willey-VCH |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | ChemCatChem |
| Jahrgang/Volume einer Zeitschrift: | 15 |
| (Heft-)Nummer: | 9 |
| Kollation: | 8 Seiten |
| DOI: | 10.26083/tuprints-00024530 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/24530 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichungsservice |
| Kurzbeschreibung (Abstract): | Despite the great potential of metal-organic frameworks (MOFs) in catalysis, industrial applications are still scarce. This is mainly due to a lack of performance when changing from idealized lab conditions towards realistic conditions of the actual application. In this work, we demonstrate the applicability and outstanding catalytic performance of an alumina-supported [Pd(2-pymo)₂]n MOF catalyst in the selective hydrogenation of acetylene to ethylene under industrial front-end conditions. It shows a competitive performance to an industrial benchmark catalyst and even exceeds it in terms of ethane selectivity due to the combination of well-defined isolated Pd active sites and synergies due to MOF-support-interactions. The high stability was proven for up to 60 h time-on-stream and supported by XPS and XRD structural analysis. |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-245301 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie |
| Hinterlegungsdatum: | 20 Nov 2023 11:31 |
| Letzte Änderung: | 21 Nov 2023 07:05 |
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| Suche nach Titel in: | TUfind oder in Google |
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- [Pd(2‐pymo)₂]n/Al₂O₃ as MOF Single Site Catalyst for the Selective Hydrogenation of Acetylene. (deposited 20 Nov 2023 11:31) [Gegenwärtig angezeigt]
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