Pfützenreuter, Rebecca ; Helmin, Marta ; Palkovits, Stefan ; Palkovits, Regina ; Rose, Marcus (2023)
Reaction network analysis and continuous production of isosorbide tert-butyl ethers.
In: Catalysis Today, 2014, 234
doi: 10.26083/tuprints-00024542
Artikel, Zweitveröffentlichung, Postprint
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Kurzbeschreibung (Abstract)
Isosorbide is considered a versatile biogenic platform compound for the production of chemicals. The functionalization of its two hydroxyl groups is challenging since they exhibit a different configuration and thus, different reactivity as well as sterical accessibility. We investigated the formation of the respective tert-butyl ethers by an addition reaction of isosorbide to isobutene heterogeneously catalyzed by acidic ion exchange resins. An efficient liquid phase process under ambient conditions in a batch reactor has been developed. The reaction network was unravelled by detailed investigation of the reaction kinetics. Additionally, the feasibility of continuous processing was successfully demonstrated on the lab-scale applying a continuously stirred-tank reactor.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2023 |
| Autor(en): | Pfützenreuter, Rebecca ; Helmin, Marta ; Palkovits, Stefan ; Palkovits, Regina ; Rose, Marcus |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Reaction network analysis and continuous production of isosorbide tert-butyl ethers |
| Sprache: | Englisch |
| Publikationsjahr: | 13 November 2023 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 1 Oktober 2014 |
| Ort der Erstveröffentlichung: | Amsterdam |
| Verlag: | Elsevier |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Catalysis Today |
| Jahrgang/Volume einer Zeitschrift: | 234 |
| DOI: | 10.26083/tuprints-00024542 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/24542 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichungsservice |
| Kurzbeschreibung (Abstract): | Isosorbide is considered a versatile biogenic platform compound for the production of chemicals. The functionalization of its two hydroxyl groups is challenging since they exhibit a different configuration and thus, different reactivity as well as sterical accessibility. We investigated the formation of the respective tert-butyl ethers by an addition reaction of isosorbide to isobutene heterogeneously catalyzed by acidic ion exchange resins. An efficient liquid phase process under ambient conditions in a batch reactor has been developed. The reaction network was unravelled by detailed investigation of the reaction kinetics. Additionally, the feasibility of continuous processing was successfully demonstrated on the lab-scale applying a continuously stirred-tank reactor. |
| Freie Schlagworte: | Isosorbide, Ion exchange resin, Etherification, Reaction kinetics, Continuous process |
| Status: | Postprint |
| URN: | urn:nbn:de:tuda-tuprints-245421 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie |
| Hinterlegungsdatum: | 13 Nov 2023 16:02 |
| Letzte Änderung: | 14 Nov 2023 13:25 |
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| Suche nach Titel in: | TUfind oder in Google |
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- Reaction network analysis and continuous production of isosorbide tert-butyl ethers. (deposited 13 Nov 2023 16:02) [Gegenwärtig angezeigt]
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